The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene

Martin, Adam D.; Easun, Timothy L.; Argent, Stephen P.; Lewis, William; Blake, Alexander J.; Schr�der, Martin

Abstract

Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2.

Citation

Martin, A. D., Easun, T. L., Argent, S. P., Lewis, W., Blake, A. J., & Schröder, M. (2016). The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene. CrystEngComm, 19(4), 603-607. https://doi.org/10.1039/c6ce01965j

• Journal Article Type: Article
• Acceptance Date: Oct 1, 2016
• Online Publication Date: Nov 16, 2016
• Publication Date: Nov 16, 2016
• Deposit Date: Nov 25, 2016
• Publicly Available Date: Nov 25, 2016
• Journal: CrystEngComm
• Electronic ISSN: 1466-8033
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 19
• Issue: 4
• Pages: 603-607
• DOI: https://doi.org/10.1039/c6ce01965j
• Public URL: https://nottingham-repository.worktribe.com/output/828280
• Publisher URL: http://pubs.rsc.org/en/Content/ArticleLanding/2017/CE/C6CE01965J#!divAbstract
• Additional Information: : This document is CrossCheck deposited; : Supplementary Information; : Crystal Structure Data; : William Lewis (ResearcherID); : Martin Schröder (ORCID); : The Royal Society of Chemistry has an exclusive publication licence for this journal; OPEN ACCESS: This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0); : Received 9 September 2016; Accepted 1 October 2016; Advance Article published 16 November 2016; Version of Record published 23 January 2017