Mohammed Noori
Tuning the electrical conductance of metalloporphyrin supramolecular wires
Noori, Mohammed; Aragones, Albert C.; Di Palma, Giuseppe; Darwish, Nadium; Bailey, Steven W.D.; Al-Galiby, Quisy; Grace, Iain; Amabilino, David B.; Gonzalez-Campo, Ar�ntzazu; D�ez-P�rez, Ismael; Colin J., Lambert
Authors
Albert C. Aragones
Giuseppe Di Palma
Nadium Darwish
Steven W.D. Bailey
Quisy Al-Galiby
Iain Grace
David B. Amabilino
Ar�ntzazu Gonzalez-Campo
Ismael D�ez-P�rez
Lambert Colin J.
Abstract
In contrast with conventional single-molecule junctions, in which the current flows parallel to the long axis or plane of a molecule, we investigate the transport properties of M(II)-5,15-diphenylporphyrin (M-DPP) single-molecule junctions (M=Co, Ni, Cu, or Zn divalent metal ions), in which the current flows perpendicular to the plane of the porphyrin. Novel STM-based conductance measurements combined with quantum transport calculations demonstrate that current-perpendicular-to-the-plane (CPP) junctions have three-orders-of-magnitude higher electrical conductanc than their current in-plane (CIP) counterparts, ranging from 2.10?2 G0 for Ni-DPP up to 8.10?2 G0 for Zn-DPP. The metal ion in the center of the DPP skeletons is strongly coordinated with the nitrogens of the pyridyl coated electrodes, with a binding energy that is sensitive to the choice of metal ion. We find that the binding energies of Zn-DPP and Co-DPP are significantly higher than those of Ni-DPP and Cu-DPP. Therefore when combined with its higher conductance, we identify Zn-DPP as the favoured candidate for high conductance CPP single-molecule devices.
Citation
Noori, M., Aragones, A. C., Di Palma, G., Darwish, N., Bailey, S. W., Al-Galiby, Q., …Colin J., L. (in press). Tuning the electrical conductance of metalloporphyrin supramolecular wires. Scientific Reports, 6, Article 37352. https://doi.org/10.1038/srep37352
Journal Article Type | Article |
---|---|
Acceptance Date | Oct 21, 2016 |
Online Publication Date | Nov 21, 2016 |
Deposit Date | Dec 20, 2016 |
Publicly Available Date | Dec 20, 2016 |
Journal | Scientific Reports |
Electronic ISSN | 2045-2322 |
Publisher | Nature Publishing Group |
Peer Reviewed | Peer Reviewed |
Volume | 6 |
Article Number | 37352 |
DOI | https://doi.org/10.1038/srep37352 |
Public URL | https://nottingham-repository.worktribe.com/output/827684 |
Publisher URL | http://www.nature.com/articles/srep37352 |
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Copyright Statement
Copyright information regarding this work can be found at the following address: http://creativecommons.org/licenses/by/4.0
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