Coordination Chemistry of 2,2′-Bipyridyl- and 2,2′:6′,2″-Terpyridyl-Substituted BEDT-TTFs: Formation of a Supramolecular Capsule Motif by the Iron(II) Tris Complex of 2,2′-Bipyridine-4-thiomethyl-BEDT-TTF

Wang, Qiang; Martin, Lee; Blake, Alexander J.; Day, Peter; Akutsu, Hiroki; Wallis, John D.

Abstract

Molecules of tris(2,2’-bipyridine-4-thiomethyl-BEDT-TTF)iron(II) (BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene) assemble in pairs to form a novel supramolecular capsular structure in the solid state. Three BEDT-TTF residues from one complex lie in the three grooves between coordinated bipyridines of the other complex, and vice versa, to form a capsule with three-fold rotational symmetry and an internal volume of ca. 160 Å3. Further aspects of the coordination chemistry of this ligand, its 6-substituted isomer and the 2,2’:6’2’’- terpyridyl-4’-thiomethyl-BEDT-TTF analogue are described.

Citation

Wang, Q., Martin, L., Blake, A. J., Day, P., Akutsu, H., & Wallis, J. D. (2016). Coordination Chemistry of 2,2′-Bipyridyl- and 2,2′:6′,2″-Terpyridyl-Substituted BEDT-TTFs: Formation of a Supramolecular Capsule Motif by the Iron(II) Tris Complex of 2,2′-Bipyridine-4-thiomethyl-BEDT-TTF. Inorganic Chemistry, 55(17), 8543-8551. https://doi.org/10.1021/acs.inorgchem.6b01101

• Journal Article Type: Article
• Acceptance Date: Aug 12, 2016
• Online Publication Date: Aug 12, 2016
• Publication Date: Sep 6, 2016
• Deposit Date: Oct 24, 2016
• Publicly Available Date: Oct 24, 2016
• Journal: Inorganic Chemistry
• Print ISSN: 0020-1669
• Electronic ISSN: 1520-510X
• Publisher: American Chemical Society
• Peer Reviewed: Peer Reviewed
• Volume: 55
• Issue: 17
• Pages: 8543-8551
• DOI: https://doi.org/10.1021/acs.inorgchem.6b01101
• Public URL: https://nottingham-repository.worktribe.com/output/819156
• Publisher URL: http://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.6b01101
• Related Public URLs: http://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.6b01101; http://pubs.acs.org/page/inocaj/about.html
• Additional Information: This document is the unedited author's version of a Submitted Work that was subsequently accepted for publication in Inorganic Chemistry, copyright © American Chemical Society after peer review. To access the final edited and published work, see http://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.6b01101.
• Contract Date: Oct 24, 2016