Skip to main content

Research Repository

Advanced Search

Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study

O'Connor, Alice E.; Mirzadeh, Nedaossadat; Bhargava, Suresh; Easun, Timothy L.; Schr�der, Martin; Blake, Alexander J.

Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study Thumbnail


Authors

Alice E. O'Connor

Nedaossadat Mirzadeh

Suresh Bhargava

Timothy L. Easun

Martin Schr�der

Alexander J. Blake



Abstract

High pressure crystallographic studies on [1,4 C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.

Citation

O'Connor, A. E., Mirzadeh, N., Bhargava, S., Easun, T. L., Schröder, M., & Blake, A. J. (2016). Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study. Chemical Communications, 52(41), 6269-6772. https://doi.org/10.1039/C6CC00923A

Journal Article Type Article
Acceptance Date Mar 11, 2016
Publication Date Mar 11, 2016
Deposit Date Jul 29, 2016
Publicly Available Date Jul 29, 2016
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 52
Issue 41
Pages 6269-6772
DOI https://doi.org/10.1039/C6CC00923A
Keywords High pressure, gold complexes, structure determination, spectroscopy, intermolecular interactions
Public URL https://nottingham-repository.worktribe.com/output/780678
Publisher URL http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC00923A#!divAbstract

Files




Downloadable Citations