Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation

Fearnley, A.F.; An, J.; Jackson, M.; Lindovska, P.; Denton, R.M.

Abstract

We report a synthesis method for the construction of quaternary aryl phoshonium salts at ambient temperature. The regiospecific reaction invovles the coupling of phosphines with aryl radicals derived from diaryliodonium salts under photoredox conditions.

Citation

Fearnley, A., An, J., Jackson, M., Lindovska, P., & Denton, R. (2016). Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation. Chemical Communications, 52, https://doi.org/10.1039/C6CC00556J

• Journal Article Type: Article
• Acceptance Date: Feb 10, 2016
• Publication Date: Feb 12, 2016
• Deposit Date: Mar 8, 2016
• Publicly Available Date: Mar 8, 2016
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 52
• DOI: https://doi.org/10.1039/C6CC00556J
• Public URL: https://nottingham-repository.worktribe.com/output/776441
• Publisher URL: http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC00556J#!divAbstract
• Contract Date: Mar 8, 2016