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Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation

Fearnley, A.F.; An, J.; Jackson, M.; Lindovska, P.; Denton, R.M.

Authors

A.F. Fearnley

J. An

M. Jackson

P. Lindovska

ROSS DENTON ross.denton@nottingham.ac.uk
Professor of Organic Chemistry



Abstract

We report a synthesis method for the construction of quaternary aryl phoshonium salts at ambient temperature. The regiospecific reaction invovles the coupling of phosphines with aryl radicals derived from diaryliodonium salts under photoredox conditions.

Citation

Fearnley, A., An, J., Jackson, M., Lindovska, P., & Denton, R. (2016). Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation. Chemical Communications, 52, https://doi.org/10.1039/C6CC00556J

Journal Article Type Article
Acceptance Date Feb 10, 2016
Publication Date Feb 12, 2016
Deposit Date Mar 8, 2016
Publicly Available Date Mar 8, 2016
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 52
DOI https://doi.org/10.1039/C6CC00556J
Public URL http://eprints.nottingham.ac.uk/id/eprint/32151
Publisher URL http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC00556J#!divAbstract
Copyright Statement Copyright information regarding this work can be found at the following address: http://eprints.nottingham.ac.uk/end_user_agreement.pdf

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Phosphonium paper for deposition.pdf (418 Kb)
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Copyright Statement
Copyright information regarding this work can be found at the following address: http://eprints.nottingham.ac.uk/end_user_agreement.pdf





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