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Copper-catalyzed borylative coupling of vinylazaarenes and N-Boc imines

Smith, Joshua J.; Best, Daniel; Lam, Hon Wai

Authors

Joshua J. Smith

Daniel Best

HON LAM Hon.Lam@nottingham.ac.uk
Professor of Sustainable Chemistry



Abstract

Cu-catalyzed three-component couplings of vinylazaarenes, B2(pin)2, and N-Boc imines are described. Oxidation of the initially formed boronate gives azaarene-containing, Boc-protected amino alcohols with reasonable to good diastereoselectivities.

Citation

Smith, J. J., Best, D., & Lam, H. W. (2016). Copper-catalyzed borylative coupling of vinylazaarenes and N-Boc imines. Chemical Communications, doi:10.1039/C6CC00603E

Journal Article Type Article
Publication Date Feb 17, 2016
Deposit Date Feb 18, 2016
Publicly Available Date Feb 18, 2016
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
DOI https://doi.org/10.1039/C6CC00603E
Public URL http://eprints.nottingham.ac.uk/id/eprint/31806
Publisher URL http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC00603E#!divAbstract
Copyright Statement Copyright information regarding this work can be found at the following address: http://eprints.nottingham.ac.uk/end_user_agreement.pdf

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HWL JoshDan Vinylazaarene Borylative Coupling with Imines Submission (Revised) Feb 2016.pdf (717 Kb)
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Copyright Statement
Copyright information regarding this work can be found at the following address: http://eprints.nottingham.ac.uk/end_user_agreement.pdf





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