Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors

Penders, In�s G. T. M.; Amara, Zacharias; Horvath, Raphael; Rossen, Kai; Poliakoff, Martyn; George, Michael W.

Abstract

The photocatalytic oxidation of mono- and di-substituted arylboronic acids to phenols has been investigated using a continuous flow photoreactor fitted with white LEDs. An EtOH–H2O solvent system accelerated conversion at 2 MPa; whereas reactions at atmospheric pressure allowed for moderately efficient desymmetrisation.

Citation

Penders, I. G. T. M., Amara, Z., Horvath, R., Rossen, K., Poliakoff, M., & George, M. W. (in press). Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors. RSC Advances, 5(9), https://doi.org/10.1039/c4ra15588b

• Journal Article Type: Article
• Acceptance Date: Dec 17, 2014
• Online Publication Date: Dec 17, 2014
• Deposit Date: Oct 19, 2017
• Publicly Available Date: Oct 19, 2017
• Journal: RSC Advances (Deleted)
• Print ISSN: 2046-2069
• Electronic ISSN: 2046-2069
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 5
• Issue: 9
• DOI: https://doi.org/10.1039/c4ra15588b
• Public URL: https://nottingham-repository.worktribe.com/output/740804
• Publisher URL: http://pubs.rsc.org/en/Content/ArticleLanding/2015/RA/C4RA15588B#!divAbstract