Skip to main content

Research Repository

Advanced Search

A Robust Binary Supramolecular Organic Framework (SOF) with High CO2 Adsorption and Selectivity

L�, Jian; Perez-Krap, Cristina; Suyetin, Mikhail; Alsmail, Nada H.; Yan, Yong; Yang, Sihai; Lewis, William; Bichoutskaia, Elena; Tang, Chiu C.; Blake, Alexander J.; Cao, Rong; Schr�der, Martin

A Robust Binary Supramolecular Organic Framework (SOF) with High CO2 Adsorption and Selectivity Thumbnail


Authors

Jian L�

Cristina Perez-Krap

Mikhail Suyetin

Nada H. Alsmail

Yong Yan

Sihai Yang

William Lewis

Chiu C. Tang

Alexander J. Blake

Rong Cao

Martin Schr�der



Abstract

A robust binary hydrogen-bonded supramolecular organic framework (SOF-7) has been synthesized by solvothermal reaction of 1,4-bis-(4-(3,5-dicyano-2,6 dipyridyl)dihydropyridyl)benzene (1) and 5,5’-bis-(azanediyl)-oxalyl-diisophthalic acid (2). Single crystal X-ray diffraction analysis shows that SOF-7 comprises 2 and 1,4-bis-(4-(3,5-dicyano-2,6-dipyridyl)pyridyl)benzene (3), the latter formed in situ from the oxidative dehydrogenation of 1. SOF-7 shows a three-dimensional four-fold interpenetrat-ed structure with complementary O−H···N hydrogen bonds to form channels that are decorated with cyano- and amide-groups. SOF-7 exhibits excellent thermal stability and sol-vent and moisture durability, as well as permanent porosity. The activated desolvated material SOF-7a shows high CO2 sorption capacity and selectivity compared with other po-rous organic materials assembled solely through hydrogen bonding.

Citation

Lü, J., Perez-Krap, C., Suyetin, M., Alsmail, N. H., Yan, Y., Yang, S., …Schröder, M. (2014). A Robust Binary Supramolecular Organic Framework (SOF) with High CO2 Adsorption and Selectivity. Journal of the American Chemical Society, 136(37), 12828-12831. https://doi.org/10.1021/ja506577g

Journal Article Type Article
Acceptance Date Jun 30, 2014
Online Publication Date Sep 3, 2014
Publication Date Sep 17, 2014
Deposit Date Aug 24, 2016
Publicly Available Date Aug 24, 2016
Journal Journal of the American Chemical Society
Print ISSN 0002-7863
Electronic ISSN 1520-5126
Publisher American Chemical Society
Peer Reviewed Peer Reviewed
Volume 136
Issue 37
Pages 12828-12831
DOI https://doi.org/10.1021/ja506577g
Public URL https://nottingham-repository.worktribe.com/output/735776
Publisher URL http://pubs.acs.org/doi/abs/10.1021/ja506577g

Files




You might also like



Downloadable Citations