Thin film synthesis of hybrid ultramicroporous materials (HUMs)- a comparative approach

Warfsmann, Jan; Tokay, Begum; Champness, Neil R.

Abstract

© 2020 The thin-film synthesis of the hybrid ultramicroporous material (HUM) TIFSIX-3-Ni on glass substrates are reported for the first time. Several methods of film formation are employed including dip-coating, seeding and secondary growth, vapour-assisted conversion, rapid thermal deposition and in-situ coating. Using the in-situ approach with dimethylformamide as solvent, we were able to grow homogeneous TIFSIX-3-Ni films at relatively low temperatures (85 °C) and short times (5 h) without substrate modification. During this study, we also significantly reduced the TIFSIX powder synthesis time to 15 h.

Citation

Warfsmann, J., Tokay, B., & Champness, N. R. (2021). Thin film synthesis of hybrid ultramicroporous materials (HUMs)- a comparative approach. Microporous and Mesoporous Materials, 311, Article 110686. https://doi.org/10.1016/j.micromeso.2020.110686

• Journal Article Type: Article
• Acceptance Date: Oct 10, 2020
• Online Publication Date: Oct 17, 2020
• Publication Date: Feb 1, 2021
• Deposit Date: Nov 27, 2020
• Publicly Available Date: Oct 18, 2021
• Journal: Microporous and Mesoporous Materials
• Print ISSN: 1387-1811
• Electronic ISSN: 1387-1811
• Publisher: Elsevier
• Peer Reviewed: Peer Reviewed
• Volume: 311
• Article Number: 110686
• DOI: https://doi.org/10.1016/j.micromeso.2020.110686
• Keywords: General Materials Science; Mechanics of Materials; General Chemistry; Condensed Matter Physics
• Public URL: https://nottingham-repository.worktribe.com/output/4986680
• Publisher URL: https://www.sciencedirect.com/science/article/abs/pii/S1387181120306867?via%3Dihub
• Additional Information: This article is maintained by: Elsevier; Article Title: Thin film synthesis of hybrid ultramicroporous materials (HUMs)- a comparative approach; Journal Title: Microporous and Mesoporous Materials; CrossRef DOI link to publisher maintained version: https://doi.org/10.1016/j.micromeso.2020.110686; Content Type: article; Copyright: © 2020 Elsevier Inc. All rights reserved.