Archibald Frank Ankrah
Heavy Metal Removal from Aqueous Solutions Using Fly-Ash Derived Zeolite NaP1
Ankrah, Archibald Frank; Tokay, Begum; Snape, Colin E.
Authors
BEGUM PEISSEL BEGUM.TOKAY@NOTTINGHAM.AC.UK
Professor of Chemical Engineering
COLIN SNAPE COLIN.SNAPE@NOTTINGHAM.AC.UK
Professor of Chemical Technology & Chemical Eng
Abstract
Fly-ash derived zeolites have recently -received great attention as cheaper adsorbents to remove heavy metals from water since they can be synthesized from a waste product. In this study, we evaluated the single- and multi-cation adsorption efficiencies of fly-ash derived NaP1 for the removal of zinc (Zn), copper (Cu) and lead (Pb). We also determined precipitation and leaching from NaP1 during the adsorption. Results showed that the uptake capacities for Zn (34mg/g) and Pb (192mg/g) were higher than other fly-ash derived NaP1 and adsorbents such as clinoptilolite and activated carbon. The Cu uptake was estimated ~ 14.6mg/g. Pb2+ > Cu2+ > Zn2+ is the order for the metal cation selectivity of NaP1. Langmuir adsorption isotherm and pseudo-second order kinetic model fitted best for all elements. The metal uptake occurred in 15min. Diffusion of hydrated metals through microporous channels is the rate-determining step.
Journal Article Type | Article |
---|---|
Acceptance Date | Feb 8, 2022 |
Online Publication Date | Mar 3, 2022 |
Publication Date | Apr 1, 2022 |
Deposit Date | Mar 7, 2022 |
Publicly Available Date | Mar 7, 2022 |
Journal | International Journal of Environmental Research |
Print ISSN | 1735-6865 |
Electronic ISSN | 2008-2304 |
Publisher | Springer Science and Business Media LLC |
Peer Reviewed | Peer Reviewed |
Volume | 16 |
Issue | 2 |
Article Number | 17 |
DOI | https://doi.org/10.1007/s41742-022-00395-9 |
Keywords | General Environmental Science |
Public URL | https://nottingham-repository.worktribe.com/output/7545946 |
Publisher URL | https://link.springer.com/article/10.1007/s41742-022-00395-9 |
Files
Heavy Metal Removal from Aqueous Solutions
(934 Kb)
PDF
Publisher Licence URL
https://creativecommons.org/licenses/by/4.0/
You might also like
Regenerability of fly-ash derived zeolite NaP1: Evaluation via copper recovery
(2022)
Journal Article
Downloadable Citations
About Repository@Nottingham
Administrator e-mail: discovery-access-systems@nottingham.ac.uk
This application uses the following open-source libraries:
SheetJS Community Edition
Apache License Version 2.0 (http://www.apache.org/licenses/)
PDF.js
Apache License Version 2.0 (http://www.apache.org/licenses/)
Font Awesome
SIL OFL 1.1 (http://scripts.sil.org/OFL)
MIT License (http://opensource.org/licenses/mit-license.html)
CC BY 3.0 ( http://creativecommons.org/licenses/by/3.0/)
Powered by Worktribe © 2024
Advanced Search