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A transition metal–gallium cluster formed via insertion of “GaI”

Blundell, Toby J.; Taylor, Laurence J.; Valentine, Andrew J.; Lewis, William; Blake, Alexander J.; McMaster, Jonathan; Kays, Deborah L.

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Authors

Toby J. Blundell

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LAURENCE TAYLOR Laurence.Taylor@nottingham.ac.uk
Teaching Associate in Organic Chemistry

Andrew J. Valentine

William Lewis

Alexander J. Blake

DEBORAH KAYS DEBORAH.KAYS@NOTTINGHAM.AC.UK
Professor of Inorganic Chemistry



Abstract

The reaction between a two-coordinate Co(II) diaryl complex and “GaI” affords 2,6-Pmp2C6H3CoGa3I5, in a new geometry for a heavier group 13-transition metal cluster. Experimental and computational investigations show that this compound is best described as a nido metalla-group 13 cluster.

Citation

Blundell, T. J., Taylor, L. J., Valentine, A. J., Lewis, W., Blake, A. J., McMaster, J., & Kays, D. L. (2020). A transition metal–gallium cluster formed via insertion of “GaI”. Chemical Communications, 56(58), 8139-8142. https://doi.org/10.1039/d0cc03559a

Journal Article Type Article
Acceptance Date Jun 9, 2020
Online Publication Date Jun 12, 2020
Publication Date Jul 25, 2020
Deposit Date Jun 19, 2020
Publicly Available Date Mar 28, 2024
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 56
Issue 58
Pages 8139-8142
DOI https://doi.org/10.1039/d0cc03559a
Keywords Materials Chemistry; Electronic, Optical and Magnetic Materials; General Chemistry; Surfaces, Coatings and Films; Metals and Alloys; Ceramics and Composites; Catalysis
Public URL https://nottingham-repository.worktribe.com/output/4678490
Publisher URL https://pubs.rsc.org/en/content/articlelanding/2020/CC/D0CC03559A#!divAbstract
Additional Information : This document is Similarity Check deposited; : Supplementary Information; : Crystal Structure Data; : Toby J. Blundell (ORCID); : Laurence J. Taylor (ORCID); : Andrew J. Valentine (ORCID); : William Lewis (ORCID); : William Lewis (ResearcherID); : Alexander J. Blake (ORCID); : Alexander J. Blake (ResearcherID); : Jonathan McMaster (ORCID); : Jonathan McMaster (ResearcherID); : Deborah L. Kays (ORCID); : Authors can choose between single-blind and double-blind peer review; : Received 18 May 2020; Accepted 9 June 2020; Accepted Manuscript published 12 June 2020; Advance Article published 17 June 2020

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