A transition metal–gallium cluster formed via insertion of “GaI”

Blundell, Toby J.; Taylor, Laurence J.; Valentine, Andrew J.; Lewis, William; Blake, Alexander J.; McMaster, Jonathan; Kays, Deborah L.

Abstract

The reaction between a two-coordinate Co(II) diaryl complex and “GaI” affords 2,6-Pmp2C6H3CoGa3I5, in a new geometry for a heavier group 13-transition metal cluster. Experimental and computational investigations show that this compound is best described as a nido metalla-group 13 cluster.

Citation

Blundell, T. J., Taylor, L. J., Valentine, A. J., Lewis, W., Blake, A. J., McMaster, J., & Kays, D. L. (2020). A transition metal–gallium cluster formed via insertion of “GaI”. Chemical Communications, 56(58), 8139-8142. https://doi.org/10.1039/d0cc03559a

• Journal Article Type: Article
• Acceptance Date: Jun 9, 2020
• Online Publication Date: Jun 12, 2020
• Publication Date: Jul 25, 2020
• Deposit Date: Jun 19, 2020
• Publicly Available Date: Jun 13, 2021
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 56
• Issue: 58
• Pages: 8139-8142
• DOI: https://doi.org/10.1039/d0cc03559a
• Keywords: Materials Chemistry; Electronic, Optical and Magnetic Materials; General Chemistry; Surfaces, Coatings and Films; Metals and Alloys; Ceramics and Composites; Catalysis
• Public URL: https://nottingham-repository.worktribe.com/output/4678490
• Publisher URL: https://pubs.rsc.org/en/content/articlelanding/2020/CC/D0CC03559A#!divAbstract
• Additional Information: : This document is Similarity Check deposited; : Supplementary Information; : Crystal Structure Data; : Toby J. Blundell (ORCID); : Laurence J. Taylor (ORCID); : Andrew J. Valentine (ORCID); : William Lewis (ORCID); : William Lewis (ResearcherID); : Alexander J. Blake (ORCID); : Alexander J. Blake (ResearcherID); : Jonathan McMaster (ORCID); : Jonathan McMaster (ResearcherID); : Deborah L. Kays (ORCID); : Authors can choose between single-blind and double-blind peer review; : Received 18 May 2020; Accepted 9 June 2020; Accepted Manuscript published 12 June 2020; Advance Article published 17 June 2020