X-ray photoelectron spectroscopy of piperidinium ionic liquids: a comparison to the charge delocalised pyridinium analogues

Men, Shuang; Licence, Peter; Do-Thanh, Chi Linh; Luo, Huimin; Dai, Sheng

Abstract

In this study, nine piperidinium-based ionic liquids are analysed by X-ray photoelectron spectroscopy. The effect of alkyl substituent length and the nature of the anion on the electronic environment of the cation are investigated. The electronic environment of the hetero carbon and the cationic nitrogen is compared between two structurally similar cations, 1-octyl-1-methylpiperidinium ([C8C1Pip]+)versus1-octylpyridinium ([C8Py]+). Due to the charge delocalisation, the hetero carbon component within [C8Py]+is more positively charged, which exhibits much higher binding energy; whilst the cationic nitrogen component is in the similar electronic environment. The impact of the charge delocalisation on the electronic environment of the anion is also compared between [C8C1Pip]+and [C8Py]+. It is found that for the more basic anion, the cation can significantly affect the electronic environment of the anion; for the less basic anion, such an effect concentrates on the component bearing more negative point charges.

Citation

Men, S., Licence, P., Do-Thanh, C. L., Luo, H., & Dai, S. (2020). X-ray photoelectron spectroscopy of piperidinium ionic liquids: a comparison to the charge delocalised pyridinium analogues. Physical Chemistry Chemical Physics, 22(21), 11976-11983. https://doi.org/10.1039/d0cp01454k

• Journal Article Type: Article
• Acceptance Date: May 6, 2020
• Online Publication Date: May 6, 2020
• Publication Date: Jun 7, 2020
• Deposit Date: Nov 27, 2020
• Publicly Available Date: May 7, 2021
• Journal: Physical Chemistry Chemical Physics
• Print ISSN: 1463-9076
• Electronic ISSN: 1463-9084
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 22
• Issue: 21
• Pages: 11976-11983
• DOI: https://doi.org/10.1039/d0cp01454k
• Keywords: Piperidinium, Ionic liquids, X-ray photoelectron spectroscopy, Cation-anion interactions
• Public URL: https://nottingham-repository.worktribe.com/output/4501150
• Publisher URL: https://pubs.rsc.org/en/content/articlelanding/2020/CP/D0CP01454K#!divAbstract