Gudrun Goretzki
Bis-morpholine-substituted perylene bisimides: Impact of isomeric arrangement on electrochemical and spectroelectrochemical properties
Goretzki, Gudrun; Davies, E. Stephen; Argent, Stephen P.; Alsindi, Wassim Z.; Blake, Alexander J.; Warren, John E.; McMaster, Jonathan; Champness, Neil R.
Authors
STEPHEN DAVIES e.s.davies@nottingham.ac.uk
Research Officer
STEPHEN ARGENT stephen.argent@nottingham.ac.uk
Senior Research Fellow
Wassim Z. Alsindi
Alexander J. Blake
John E. Warren
JONATHAN MCMASTER Jonathan.McMaster@nottingham.ac.uk
Professor of Chemistry
Neil R. Champness
Abstract
(Graph Presented) The synthesis and separation of the 1,6- and 1,7- isomers of N,N′-bis(n-butyl)dimorpholino-3,4:9,10-perylenetetracarboxylic acid bisimide are reported. Investigations of the electrochemical and spectroscopic, in particular, spectroelectrochemical, properties of the two isomers reveal a sequence of electrochemically and chemically reversible redox processes for both isomers. Importantly, the 1,7-isomer of N,N′-bis(n-butyl)dimorpholino-3, 4:9,10-perylenetetracarboxylic acid bisimide was observed to undergo a two-electron oxidation process, which contrasts with the behavior of both the corresponding 1,6-isomer and other related amino-substituted perylene bis-imide species. © 2008 American Chemical Society.
Citation
Goretzki, G., Davies, E. S., Argent, S. P., Alsindi, W. Z., Blake, A. J., Warren, J. E., …Champness, N. R. (2008). Bis-morpholine-substituted perylene bisimides: Impact of isomeric arrangement on electrochemical and spectroelectrochemical properties. Journal of Organic Chemistry, 73(22), 8808-8814. https://doi.org/10.1021/jo801557e
Journal Article Type | Article |
---|---|
Acceptance Date | Jul 18, 2008 |
Online Publication Date | Oct 15, 2008 |
Publication Date | Nov 21, 2008 |
Deposit Date | Jul 3, 2020 |
Journal | Journal of Organic Chemistry |
Print ISSN | 0022-3263 |
Publisher | American Chemical Society |
Peer Reviewed | Peer Reviewed |
Volume | 73 |
Issue | 22 |
Pages | 8808-8814 |
DOI | https://doi.org/10.1021/jo801557e |
Public URL | https://nottingham-repository.worktribe.com/output/3109205 |
Publisher URL | https://pubs.acs.org/doi/10.1021/jo801557e |
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