Jonathan C. Moore
In Situ Sulfidation of Pd/C: A Straightforward Method for Chemoselective Conjugate Reduction by Continuous Hydrogenation
Moore, Jonathan C.; Howie, Rowena A.; Bourne, Samuel L.; Jenkins, Gareth N.; Licence, Peter; Poliakoff, Martyn; George, Michael W.
Rowena A. Howie
Samuel L. Bourne
Gareth N. Jenkins
Michael W. George
A method has been developed for the in situ sulfidation of Pd/C under continuous flow. The approach provides a cheap, sustainable, and operationally convenient method for chemoselective conjugate reduction by continuous hydrogenation. High conversions and excellent selectivities were obtained for olefin reduction in α/β-unsaturated carbonyl compounds in the presence of hydrogenatively sensitive functionalities. The methodology was analyzed with a green metric system to highlight the sustainability features of the process.
|Journal Article Type||Article|
|Publication Date||Oct 7, 2019|
|Journal||ACS Sustainable Chemistry & Engineering|
|Publisher||American Chemical Society|
|Peer Reviewed||Peer Reviewed|
|APA6 Citation||Moore, J. C., Howie, R. A., Bourne, S. L., Jenkins, G. N., Licence, P., Poliakoff, M., & George, M. W. (2019). In Situ Sulfidation of Pd/C: A Straightforward Method for Chemoselective Conjugate Reduction by Continuous Hydrogenation. ACS Sustainable Chemistry and Engineering, 7(19), 16814-16819. https://doi.org/10.1021/acssuschemeng.9b04347|
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