Hydraulic and biotic impacts on neutralisation of high-pH waters

Gomes, Helena I.; Rogerson, Mike; Burke, Ian T.; Stewart, Douglas I.; Mayes, William M.

Abstract

The management of alkaline (pH 11–12.5) leachate is an important issue associated with the conditioning, afteruse or disposal of steel slags. Passive in-gassing of atmospheric CO2 is a low cost option for reducing Ca(OH)2 alkalinity, as Ca(OH)2 is neutralised by carbonic acid to produce CaCO3. The relative effectiveness of such treatment can be affected by both the system geometry (i.e. stepped cascades versus settlement ponds) and biological colonization. Sterilized mesocosm experiments run over periods of 20 days showed that, due to more water mixing and enhanced CO2 dissolution at the weirs, the cascade systems (pH 11.2 → 9.6) are more effective than settlement ponds (pH 11.2 → 11.0) for lowering leachate alkalinity in all the tested conditions. The presence of an active microbial biofilm resulted in significantly more pH reduction in ponds (pH 11.2 → 9.5), but had a small impact on the cascade systems (pH 11.2 → 9.4). The pH variation in biofilm colonized systems shows a diurnal cycle of 1 to 1.5 pH units due to CO2 uptake and release associated with respiration and photosynthesis. The results demonstrate that, where gradient permits, aeration via stepped cascades are the best option for neutralisation of steel slag leachates, and where feasible, the development of biofilm communities can also help reduce alkalinity.

Citation

Gomes, H. I., Rogerson, M., Burke, I. T., Stewart, D. I., & Mayes, W. M. (2017). Hydraulic and biotic impacts on neutralisation of high-pH waters. Science of the Total Environment, 601-602, 1271-1279. https://doi.org/10.1016/j.scitotenv.2017.05.248

• Journal Article Type: Article
• Acceptance Date: May 26, 2017
• Online Publication Date: Jun 9, 2017
• Publication Date: 2017-12
• Deposit Date: Aug 22, 2019
• Publicly Available Date: Aug 28, 2019
• Journal: Science of The Total Environment
• Print ISSN: 0048-9697
• Electronic ISSN: 1879-1026
• Publisher: Elsevier
• Peer Reviewed: Peer Reviewed
• Volume: 601-602
• Pages: 1271-1279
• DOI: https://doi.org/10.1016/j.scitotenv.2017.05.248
• Public URL: https://nottingham-repository.worktribe.com/output/2471133
• Publisher URL: https://www.sciencedirect.com/science/article/pii/S0048969717313566
• Additional Information: This article is maintained by: Elsevier; Article Title: Hydraulic and biotic impacts on neutralisation of high-pH waters; Journal Title: Science of The Total Environment; CrossRef DOI link to publisher maintained version: https://doi.org/10.1016/j.scitotenv.2017.05.248; Content Type: article; Copyright: © 2017 The Authors. Published by Elsevier B.V.
• Contract Date: Aug 22, 2019