Assessing the Accuracy of Soot Nanoparticle Morphology Measurements Using Three-Dimensional Electron Tomography

Haffner-Staton, Ephraim; La Rocca, Antonino; Cairns, Alasdair; McGhee, Michael; Fay, Mike

Abstract

Morphology plays an important role in determining behaviour and impact of soot nanoparticles, including effect on human health, atmospheric optical properties, contribution to engine wear, and role in marine ecology. However, its nanoscopic size has limited the ability to directly measure useful morphological parameters such as surface area and effective volume. Recently, 3D morphology characterization of soot nanoparticles via electron tomography has been the subject of several introductory studies. So-called '3D-TEM' has been posited as an improvement over traditional 2D-TEM characterization due to the elimination of the error-inducing information gap that exists between 3-dimensional soot structures and 2-dimensional TEM projections. Little follow-up work has been performed due to difficulties with developing methodologies into robust high-throughput techniques. Recent work by the authors has exhibited significant improvements in efficiency, though as yet due consideration has not been given to assessing fidelity of the technique. This is vital to confirm significant and tangible improvements in soot-characterization accuracy that will establish 3D-TEM as a legitimate tool. Synthetic ground-truth data was developed to closely mimic real soot structures and the 3D-TEM volume-reconstruction process. A variety of procedures were tested to assess the magnitude and nuances of deviations from ground-truth values. Results showed average Z-elongation due to the 'missing-wedge' at 3.5% for the previously developed optimized procedure. Mean deviations from ground-truth in volume and surface area were 2.0% and-0.1% respectively. Results indicate highly accurate 3D-reconstruction can be achieved with an optimized procedure that can bridge the gap to permit high-throughput 3D morphology characterization of soot.

Citation

Haffner-Staton, E., La Rocca, A., Cairns, A., McGhee, M., & Fay, M. (2019). Assessing the Accuracy of Soot Nanoparticle Morphology Measurements Using Three-Dimensional Electron Tomography. SAE Technical Papers, 2019-April, Article 2019-01-1188. https://doi.org/10.4271/2019-01-1188

• Journal Article Type: Conference Paper
• Conference Name: WCX SAE World Congress Experience
• Acceptance Date: Feb 2, 2019
• Online Publication Date: Apr 2, 2019
• Publication Date: Apr 2, 2019
• Deposit Date: Apr 1, 2019
• Publicly Available Date: Oct 9, 2019
• Journal: SAE Technical Papers
• Electronic ISSN: 0148-7191
• Publisher: SAE International
• Peer Reviewed: Peer Reviewed
• Volume: 2019-April
• Article Number: 2019-01-1188
• DOI: https://doi.org/10.4271/2019-01-1188
• Public URL: https://nottingham-repository.worktribe.com/output/1724852
• Publisher URL: https://saemobilus.sae.org/content/2019-01-1188