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The impact of sulfur functionalisation on nitrogen-based ionic liquid cations

Santos, Ana R.; Hanson-Heine, Magnus W. D.; Besley, Nicholas A.; Licence, Peter

Authors

Ana R. Santos

Magnus W. D. Hanson-Heine

NICK BESLEY nick.besley@nottingham.ac.uk
Professor of Theoretical Chemistry

Abstract

It has been demonstrated that bonding and interactions within ionic liquids (ILs) can be elegantly tuned by manipulation of structure and the the introduction of functional groups. Here we use XPS to investigate the impact of sulfur containing substituents on the electronic structure of a series N-based cations, all with a common anion, [NTf2]-. The experiments reveal complexity and perturbation of delocalised systems which cannot be easily interpretated by NMR and XPS alone, DFT provides critical insight into bonding and underpins the assignment of spectra and development of deconstruction models for each system studied.

Journal Article Type Article
Publication Date Sep 17, 2018
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 54
Pages 11403-11406
DOI https://doi.org/10.1039/c8cc05515g
Keywords Materials Chemistry; Electronic, Optical and Magnetic Materials; General Chemistry; Surfaces, Coatings and Films; Metals and Alloys; Ceramics and Composites; Catalysis
Publisher URL https://pubs.rsc.org/en/Content/ArticleLanding/2018/CC/C8CC05515G#!divAbstract
Additional Information : This document is Similarity Check deposited; : Supplementary Information; : Ana R. Santos (ORCID); : Ana R. Santos (ResearcherID); : Nicholas A. Besley (ORCID); : Nicholas A. Besley (ResearcherID); : Peter Licence (ORCID); : Peter Licence (ResearcherID); : Authors can choose between single-blind and double-blind peer review; : Received 9 July 2018; Accepted 17 September 2018; Accepted Manuscript published 17 September 2018; Advance Article published 25 September 2018

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