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Methane adsorption in metal-organic frameworks containing nanographene linkers: a computational study (2014)
Journal Article
Bichoutskaia, E., Suyetin, M., Bound, M., Yong, Y., & Schröder, M. (2014). Methane adsorption in metal-organic frameworks containing nanographene linkers: a computational study. Journal of Physical Chemistry C, 118(29), https://doi.org/10.1021/jp503210h

Metal-organic framework (MOF) materials are known to be amenable to expansion through elongation of the parent organic linker. For a family of model (3,24)-connected
MOFs with the rht topology, in which the central part of organic linker comprises a... Read More about Methane adsorption in metal-organic frameworks containing nanographene linkers: a computational study.

The Ketimide Ligand is Not Just an Inert Spectator: Heteroallene Insertion Reactivity of an Actinide-Ketimide Linkage in a Thorium Carbene Amide Ketimide Complex (2014)
Journal Article
Lu, E., Lewis, W., Blake, A. J., & Liddle, S. T. (2014). The Ketimide Ligand is Not Just an Inert Spectator: Heteroallene Insertion Reactivity of an Actinide-Ketimide Linkage in a Thorium Carbene Amide Ketimide Complex. Angewandte Chemie International Edition, 53(35), 9356-9359. https://doi.org/10.1002/anie.201404898

The ketimide anion R2C[DOUBLE BOND]N− is an important class of chemically robust ligand that binds strongly to metal ions and is considered ideal for supporting reactive metal fragments due to its inert spectator nature; this contrasts with R2N− amid... Read More about The Ketimide Ligand is Not Just an Inert Spectator: Heteroallene Insertion Reactivity of an Actinide-Ketimide Linkage in a Thorium Carbene Amide Ketimide Complex.

Dolomitization of Lower Cretaceous Peritidal Carbonates By Modified Seawater: Constraints From Clumped Isotopic Paleothermometry, Elemental Chemistry, and Strontium Isotopes (2014)
Journal Article
Sena, C. M., John, C. M., Jourdan, A.-L., Vandeginste, V., & Manning, C. (2014). Dolomitization of Lower Cretaceous Peritidal Carbonates By Modified Seawater: Constraints From Clumped Isotopic Paleothermometry, Elemental Chemistry, and Strontium Isotopes. Journal of Sedimentary Research, 84(7), 552-566. https://doi.org/10.2110/jsr.2014.45

This study investigates one of the few examples of dolomitization of Lower Cretaceous shallow-water limestonesfrom the southern Tethys carbonate platform from outcrops on the Haushi-Huqf High in central-east Oman. Mud-dominatedperitidal carbonates ri... Read More about Dolomitization of Lower Cretaceous Peritidal Carbonates By Modified Seawater: Constraints From Clumped Isotopic Paleothermometry, Elemental Chemistry, and Strontium Isotopes.

Bimolecular porous supramolecular networks deposited from solution on layered materials: graphite, boron nitride and molybdenum disulphide (2014)
Journal Article
Korolkov, V. V., Svatek, S. A., Allen, S., Roberts, C. J., Tendler, S. J., Taniguchi, T., Watanabe, K., Champness, N. R., & Beton, P. H. (2014). Bimolecular porous supramolecular networks deposited from solution on layered materials: graphite, boron nitride and molybdenum disulphide. Chemical Communications, 50(64), https://doi.org/10.1039/C4CC03720K

A two-dimensional porous network formed from perylene tetracarboxylic diimide (PTCDI) and melamine may be deposited from
solution on the surfaces of highly oriented pyrolytic graphite (HOPG), hexagonal boron nitride (hBN) and molybdenum disulphide (... Read More about Bimolecular porous supramolecular networks deposited from solution on layered materials: graphite, boron nitride and molybdenum disulphide.

Correlated defect nanoregions in a metal-organic framework (2014)
Journal Article
Cliffe, M. J., Wan, W., Zou, X., Chater, P. A., Kleppe, A. K., Tucker, M. G., Wilhelm, H., Funnell, N. P., Coudert, F.-X., & Goodwin, A. L. (2014). Correlated defect nanoregions in a metal-organic framework. Nature Communications, 5, Article 4176. https://doi.org/10.1038/ncomms5176

Throughout much of condensed matter science, correlated disorder is a key to material function. While structural and compositional defects are known to exist within a variety of metal-organic frameworks (MOFs), the prevailing understanding is that th... Read More about Correlated defect nanoregions in a metal-organic framework.

Engineering a reagentless biosensor for single-stranded DNA to measure real-time helicase activity in Bacillus (2014)
Journal Article
Green, M., Gilhooly, N. S., Abedeen, S., Scott, D. J., Dillingham, M. S., & Soultanas, P. (2014). Engineering a reagentless biosensor for single-stranded DNA to measure real-time helicase activity in Bacillus. Biosensors and Bioelectronics, 61, 579-586. https://doi.org/10.1016/j.bios.2014.06.011

Single-stranded DNA-binding protein (SSB) is a well characterized ubiquitous and essential bacterial protein involved in almost all aspects of DNA metabolism. Using the Bacillus subtilis SSB we have generated a reagentless SSB biosensor that can be u... Read More about Engineering a reagentless biosensor for single-stranded DNA to measure real-time helicase activity in Bacillus.

Quaternary ammonium and phosphonium based ionic liquids: a comparison of common anions (2014)
Journal Article
Blundell, R. K., & Licence, P. (2014). Quaternary ammonium and phosphonium based ionic liquids: a comparison of common anions. Physical Chemistry Chemical Physics, 16(29), 15278-15288. https://doi.org/10.1039/c4cp01901f

A series of ammonium-based ionic liquids and their phosphonium analogues have been investigated using X-ray Photoelectron Spectroscopy (XPS). A robust C 1s peak fitting model has been developed and described for the tetraalkylphosphonium and tetraalk... Read More about Quaternary ammonium and phosphonium based ionic liquids: a comparison of common anions.

Synthesis of spirocyclic enones by rhodium-catalyzed dearomatizing oxidative annulation of 2-alkenylphenols with alkynes and enynes (2014)
Journal Article
Kujawa, S., Best, D., Burns, D. J., & Lam, H. W. (2014). Synthesis of spirocyclic enones by rhodium-catalyzed dearomatizing oxidative annulation of 2-alkenylphenols with alkynes and enynes. Chemistry - A European Journal, 20(28), https://doi.org/10.1002/chem.201403454

The dearomatizing oxidative annulation of 2-alkenylphenols with alkynes and enynes proceeds with high yields and regioselectivities under Rh(III) catalysis. These reactions are successful using Cu(OAc)2 or air as the stoichiometric oxidant, and provi... Read More about Synthesis of spirocyclic enones by rhodium-catalyzed dearomatizing oxidative annulation of 2-alkenylphenols with alkynes and enynes.

Cyanide-Bridged Decanuclear Cobalt–Iron Cage (2014)
Journal Article
Oshio, H., Shiga, T., Newton, G. N., Tetsuka, T., Nihei, M., Sakai, K., & Sekine, Y. (2014). Cyanide-Bridged Decanuclear Cobalt–Iron Cage. Inorganic Chemistry, 53(12), 5899-5901. https://doi.org/10.1021/ic500964m

A cyanide-bridged decanuclear [Co6Fe4] cluster was synthesized by a one-pot reaction, and the magnetic properties and electronic configuration were investigated. The complex displayed thermally controlled electron-transfer-coupled spin transition (ET... Read More about Cyanide-Bridged Decanuclear Cobalt–Iron Cage.