Hiroki Oshio
Cyanide-Bridged Decanuclear Cobalt–Iron Cage
Oshio, Hiroki; Shiga, Takuya; Newton, Graham N.; Tetsuka, Tamaki; Nihei, Masayuki; Sakai, Kanae; Sekine, Yoshihiro
Authors
Takuya Shiga
GRAHAM NEWTON GRAHAM.NEWTON@NOTTINGHAM.AC.UK
Professor of Chemistry
Tamaki Tetsuka
Masayuki Nihei
Kanae Sakai
Yoshihiro Sekine
Contributors
GRAHAM NEWTON GRAHAM.NEWTON@NOTTINGHAM.AC.UK
Researcher
Abstract
A cyanide-bridged decanuclear [Co6Fe4] cluster was synthesized by a one-pot reaction, and the magnetic properties and electronic configuration were investigated. The complex displayed thermally controlled electron-transfer-coupled spin transition (ETCST) behavior between CoIII low-spin–NC–FeII low-spin and CoII high-spin–NC–FeIII low-spin states, as confirmed by single-crystal X-ray, magnetic, and Mössbauer analyses.
Citation
Oshio, H., Shiga, T., Newton, G. N., Tetsuka, T., Nihei, M., Sakai, K., & Sekine, Y. (2014). Cyanide-Bridged Decanuclear Cobalt–Iron Cage. Inorganic Chemistry, 53(12), 5899-5901. https://doi.org/10.1021/ic500964m
Journal Article Type | Article |
---|---|
Acceptance Date | Jun 1, 2014 |
Online Publication Date | Jun 3, 2014 |
Publication Date | Jun 16, 2014 |
Deposit Date | Feb 26, 2020 |
Publicly Available Date | Apr 29, 2020 |
Journal | Inorganic Chemistry |
Print ISSN | 0020-1669 |
Electronic ISSN | 1520-510X |
Publisher | American Chemical Society |
Peer Reviewed | Peer Reviewed |
Volume | 53 |
Issue | 12 |
Pages | 5899-5901 |
DOI | https://doi.org/10.1021/ic500964m |
Keywords | Physical and Theoretical Chemistry; Inorganic Chemistry |
Public URL | https://nottingham-repository.worktribe.com/output/4037874 |
Publisher URL | https://pubs.acs.org/doi/10.1021/ic500964m |
Additional Information | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by t he publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/ic500964m |
Files
Accepted manuscript
(415 Kb)
PDF
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