Outputs (10)

A Wavy Two-Dimensional Covalent Organic Framework from Core-Twisted Polycyclic Aromatic Hydrocarbons (2019)
Journal Article
Melle-Franco, M., Martínez-Abadía, M., Stoppiello, C. T., Strutynski, K., Lerma-Berlanga, B., Martí-Gastaldo, C., Saeki, A., Khlobystov, A. N., & Mateo-Alonso, A. (2019). A Wavy Two-Dimensional Covalent Organic Framework from Core-Twisted Polycyclic Aromatic Hydrocarbons. Journal of the American Chemical Society, 141(36), 14403-14410. https://doi.org/10.1021/jacs.9b07383

A high degree of crystallinity is an essential aspect in two-dimensional covalent organic frameworks, as many properties depend strongly on the structural arrangement of the different layers and their constituents. We introduce herein a new design st... Read More about A Wavy Two-Dimensional Covalent Organic Framework from Core-Twisted Polycyclic Aromatic Hydrocarbons.

An integrated approach to determine interactive genotoxic and global gene expression effects of multiwalled carbon nanotubes (MWCNTs) and benzo[a]pyrene (BaP) on marine mussels: evidence of reverse ‘Trojan Horse’ effects (2019)
Journal Article
Barranger, A., Rance, G. A., Aminot, Y., Dallas, L. J., Sforzini, S., Weston, N. J., Lodge, R. W., Banni, M., Arlt, V. M., Moore, M. N., Readman, J. W., Viarengo, A., Khlobystov, A. N., & Jha, A. N. (2019). An integrated approach to determine interactive genotoxic and global gene expression effects of multiwalled carbon nanotubes (MWCNTs) and benzo[a]pyrene (BaP) on marine mussels: evidence of reverse ‘Trojan Horse’ effects. Nanotoxicology, 13(10), 1324-1343. https://doi.org/10.1080/17435390.2019.1654003

The interactions between carbon-based engineered nanoparticles (ENPs) and organic pollutants might enhance the uptake of contaminants into biota. The present integrated study aimed to assess this potential ‘Trojan Horse’, probing the interactive effe... Read More about An integrated approach to determine interactive genotoxic and global gene expression effects of multiwalled carbon nanotubes (MWCNTs) and benzo[a]pyrene (BaP) on marine mussels: evidence of reverse ‘Trojan Horse’ effects.

Host–Guest Hybrid Redox Materials Self‐Assembled from Polyoxometalates and Single‐Walled Carbon Nanotubes (2019)
Journal Article
Jordan, J. W., Lowe, G. A., McSweeney, R. L., Stoppiello, C. T., Lodge, R. W., Skowron, S. T., Biskupek, J., Rance, G. A., Kaiser, U., Walsh, D. A., Newton, G. N., & Khlobystov, A. N. (2019). Host–Guest Hybrid Redox Materials Self‐Assembled from Polyoxometalates and Single‐Walled Carbon Nanotubes. Advanced Materials, 31(41), Article 1904182. https://doi.org/10.1002/adma.201904182

The development of next‐generation molecular‐electronic, electrocatalytic, and energy‐storage systems depends on the availability of robust materials in which molecular charge‐storage sites and conductive hosts are in intimate contact. It is shown he... Read More about Host–Guest Hybrid Redox Materials Self‐Assembled from Polyoxometalates and Single‐Walled Carbon Nanotubes.

Antagonistic Interactions between Benzo[a]pyrene and Fullerene (C60) in Toxicological Response of Marine Mussels (2019)
Journal Article
Barranger, A., Langan, L. M., Sharma, V., Rance, G. A., Aminot, Y., Weston, N. J., Akcha, F., Moore, M. N., Arlt, V. M., Khlobystov, A. N., Readman, J. W., & Jha, A. N. (2019). Antagonistic Interactions between Benzo[a]pyrene and Fullerene (C60) in Toxicological Response of Marine Mussels. Nanomaterials, 9(7), Article 987. https://doi.org/10.3390/nano9070987

© 2019 by the authors. Licensee MDPI, Basel, Switzerland. This study aimed to assess the ecotoxicological effects of the interaction of fullerene (C60) and benzo[a]pyrene (B[a]P) on the marine mussel, Mytilus galloprovincialis. The uptake of nC60, B[... Read More about Antagonistic Interactions between Benzo[a]pyrene and Fullerene (C60) in Toxicological Response of Marine Mussels.

Wall- and Hybridisation-Selective Synthesis of Nitrogen-Doped Double-Walled Carbon Nanotubes (2019)
Journal Article
Carini, M., Shi, L., Chamberlain, T., Liu, M., Valenti, G., Melle-Franco, M., Paolucci, F., Khlobystov, A., Pichler, T., & Mateo-Alonso, A. (2019). Wall- and Hybridisation-Selective Synthesis of Nitrogen-Doped Double-Walled Carbon Nanotubes. Angewandte Chemie International Edition, 58(30), 10276-10280. https://doi.org/10.1002/anie.201905559

Controlled nitrogen-doping is a powerful methodology to modify the properties of carbon nanostructures and produce functional materials for electrocatalysis, energy conversion and storage, and sensing, among others. Herein, we report a wall- and hybr... Read More about Wall- and Hybridisation-Selective Synthesis of Nitrogen-Doped Double-Walled Carbon Nanotubes.

Direct synthesis of multiplexed metal nanowire based devices using carbon nanotubes as vector templates (2019)
Journal Article
Clément, P., Xu, X., Stoppiello, C. T., Rance, G. A., Attanzio, A., O’Shea, J. N., Temperton, R. H., Khlobystov, A. N., Lovelock, K. R. J., Seymour, J. M., Fogarty, R. M., Baker, A., Bourne, R. A., Hall, B., Chamberlain, T. W., & Palma, M. (2019). Direct synthesis of multiplexed metal nanowire based devices using carbon nanotubes as vector templates. Angewandte Chemie International Edition, 58(29), 9928-9932. https://doi.org/10.1002/anie.201902857

We present the synthesis of metal nanowires in a multiplexed device configuration using single-walled carbon nanotubes (SWNTs) as nanoscale vector templates. The SWNT templates control the dimensionality of the wires, allowing precise control of thei... Read More about Direct synthesis of multiplexed metal nanowire based devices using carbon nanotubes as vector templates.

Core–Shell NaHoF4@TiO2 NPs: A Labeling Method to Trace Engineered Nanomaterials of Ubiquitous Elements in the Environment (2019)
Journal Article
Cui, X., Fryer, B., Zhou, D., Lodge, R. W., Khlobystov, A. N., Valsami-Jones, E., & Lynch, I. (2019). Core–Shell NaHoF4@TiO2 NPs: A Labeling Method to Trace Engineered Nanomaterials of Ubiquitous Elements in the Environment. ACS Applied Materials and Interfaces, 11(21), 19452-19461. https://doi.org/10.1021/acsami.9b03062

Understanding the fate and behavior of nanoparticles (NPs) in the natural environment is important to assess their potential risk. Single particle inductively coupled plasma mass spectrometry (spICP-MS) allows for the detection of NPs at extremely lo... Read More about Core–Shell NaHoF4@TiO2 NPs: A Labeling Method to Trace Engineered Nanomaterials of Ubiquitous Elements in the Environment.

Molybdenum dioxide in carbon nanoreactors as a catalytic nanosponge for the efficient desulfurization of liquid fuels (2019)
Journal Article
Astle, M. A., Rance, G. A., Loughlin, H. J., Peters, T. D., & Khlobystov, A. N. (2019). Molybdenum dioxide in carbon nanoreactors as a catalytic nanosponge for the efficient desulfurization of liquid fuels. Advanced Functional Materials, 29(17), Article 1808092. https://doi.org/10.1002/adfm.201808092

The principle of a “catalytic nanosponge” that combines the catalysis of organosulfur oxidation and sequestration of the products from reaction mixtures is demonstrated. Group VI metal oxide nanoparticles (CrOx, MoOx, WOx) are embedded within hollow... Read More about Molybdenum dioxide in carbon nanoreactors as a catalytic nanosponge for the efficient desulfurization of liquid fuels.

Steric and electronic control of 1,3-dipolar cycloaddition reactions in carbon nanotube nanoreactors (2019)
Journal Article
Miners, S. A., Fay, M. W., Baldoni, M., Besley, E., Khlobystov, A. N., & Rance, G. A. (2019). Steric and electronic control of 1,3-dipolar cycloaddition reactions in carbon nanotube nanoreactors. Journal of Physical Chemistry C, 123(10), 6294-6302. https://doi.org/10.1021/acs.jpcc.9b01190

The use of single-walled carbon nanotubes as effective nanoreactors for preparative bimolecular reactions has been demonstrated for the first time. We show that the extreme spatial confinement of guest reactant molecules inside host carbon nanotubes... Read More about Steric and electronic control of 1,3-dipolar cycloaddition reactions in carbon nanotube nanoreactors.

Three dimensional nanoscale analysis reveals aperiodic mesopores in a covalent organic framework and conjugated microporous polymer (2019)
Journal Article
Stoppiello, C. T., Isla, H., Martínez-Abadía, M., Fay, M. W., Parmenter, C. D. J., Roe, M. J., Lerma-Berlanga, B., Martí-Gastaldo, C., Mateo-Alonso, A., & Khlobystov, A. N. (2019). Three dimensional nanoscale analysis reveals aperiodic mesopores in a covalent organic framework and conjugated microporous polymer. Nanoscale, 11(6), 2848-2854. https://doi.org/10.1039/c8nr10086a

The integrated analytical approach developed in this study offers a powerful methodology for the structural characterization of complex molecular nanomaterials. Structures of a covalent organic framework based on boronate esters (COF-5) and a conjuga... Read More about Three dimensional nanoscale analysis reveals aperiodic mesopores in a covalent organic framework and conjugated microporous polymer.