Outputs (1527)

Bimolecular porous supramolecular networks deposited from solution on layered materials: graphite, boron nitride and molybdenum disulphide (2014)
Journal Article
Korolkov, V. V., Svatek, S. A., Allen, S., Roberts, C. J., Tendler, S. J., Taniguchi, T., …Beton, P. H. (2014). Bimolecular porous supramolecular networks deposited from solution on layered materials: graphite, boron nitride and molybdenum disulphide. Chemical Communications, 50(64), https://doi.org/10.1039/C4CC03720K

A two-dimensional porous network formed from perylene tetracarboxylic diimide (PTCDI) and melamine may be deposited from
solution on the surfaces of highly oriented pyrolytic graphite (HOPG), hexagonal boron nitride (hBN) and molybdenum disulphide (... Read More about Bimolecular porous supramolecular networks deposited from solution on layered materials: graphite, boron nitride and molybdenum disulphide.

Correlated defect nanoregions in a metal-organic framework (2014)
Journal Article
Cliffe, M. J., Wan, W., Zou, X., Chater, P. A., Kleppe, A. K., Tucker, M. G., …Goodwin, A. L. (2014). Correlated defect nanoregions in a metal-organic framework. Nature Communications, 5, Article 4176. https://doi.org/10.1038/ncomms5176

Throughout much of condensed matter science, correlated disorder is a key to material function. While structural and compositional defects are known to exist within a variety of metal-organic frameworks (MOFs), the prevailing understanding is that th... Read More about Correlated defect nanoregions in a metal-organic framework.

Optimal antisense target reducing INS intron 1 retention is adjacent to a parallel G quadruplex (2014)
Journal Article
Kralovicova, J., Searle, M., Lages, A., Patel, A., Dhir, A., Buratti, E., & Vorechovsky, I. (2014). Optimal antisense target reducing INS intron 1 retention is adjacent to a parallel G quadruplex. Nucleic Acids Research, 42(12), 8161-8173. https://doi.org/10.1093/nar/gku507

Engineering a reagentless biosensor for single-stranded DNA to measure real-time helicase activity in Bacillus (2014)
Journal Article
Green, M., Gilhooly, N. S., Abedeen, S., Scott, D. J., Dillingham, M. S., & Soultanas, P. (2014). Engineering a reagentless biosensor for single-stranded DNA to measure real-time helicase activity in Bacillus. Biosensors and Bioelectronics, 61, 579-586. https://doi.org/10.1016/j.bios.2014.06.011

Single-stranded DNA-binding protein (SSB) is a well characterized ubiquitous and essential bacterial protein involved in almost all aspects of DNA metabolism. Using the Bacillus subtilis SSB we have generated a reagentless SSB biosensor that can be u... Read More about Engineering a reagentless biosensor for single-stranded DNA to measure real-time helicase activity in Bacillus.

Quaternary ammonium and phosphonium based ionic liquids: a comparison of common anions (2014)
Journal Article
Blundell, R. K., & Licence, P. (2014). Quaternary ammonium and phosphonium based ionic liquids: a comparison of common anions. Physical Chemistry Chemical Physics, 16(29), 15278-15288. https://doi.org/10.1039/c4cp01901f

A series of ammonium-based ionic liquids and their phosphonium analogues have been investigated using X-ray Photoelectron Spectroscopy (XPS). A robust C 1s peak fitting model has been developed and described for the tetraalkylphosphonium and tetraalk... Read More about Quaternary ammonium and phosphonium based ionic liquids: a comparison of common anions.

Synthesis of spirocyclic enones by rhodium-catalyzed dearomatizing oxidative annulation of 2-alkenylphenols with alkynes and enynes (2014)
Journal Article
Kujawa, S., Best, D., Burns, D. J., & Lam, H. W. (2014). Synthesis of spirocyclic enones by rhodium-catalyzed dearomatizing oxidative annulation of 2-alkenylphenols with alkynes and enynes. Chemistry - A European Journal, 20(28), https://doi.org/10.1002/chem.201403454

The dearomatizing oxidative annulation of 2-alkenylphenols with alkynes and enynes proceeds with high yields and regioselectivities under Rh(III) catalysis. These reactions are successful using Cu(OAc)2 or air as the stoichiometric oxidant, and provi... Read More about Synthesis of spirocyclic enones by rhodium-catalyzed dearomatizing oxidative annulation of 2-alkenylphenols with alkynes and enynes.

Cyanide-Bridged Decanuclear Cobalt–Iron Cage (2014)
Journal Article
Oshio, H., Shiga, T., Newton, G. N., Tetsuka, T., Nihei, M., Sakai, K., & Sekine, Y. (2014). Cyanide-Bridged Decanuclear Cobalt–Iron Cage. Inorganic Chemistry, 53(12), 5899-5901. https://doi.org/10.1021/ic500964m

A cyanide-bridged decanuclear [Co6Fe4] cluster was synthesized by a one-pot reaction, and the magnetic properties and electronic configuration were investigated. The complex displayed thermally controlled electron-transfer-coupled spin transition (ET... Read More about Cyanide-Bridged Decanuclear Cobalt–Iron Cage.

1,4-addition of TMSCCl3to nitroalkenes: efficient reaction conditions and mechanistic understanding (2014)
Journal Article
Wu, N., Wahl, B., Woodward, S., & Lewis, W. (2014). 1,4-addition of TMSCCl3to nitroalkenes: efficient reaction conditions and mechanistic understanding. Chemistry - A European Journal, 20(25), https://doi.org/10.1002/chem.201402394

Improved synthetic conditions allow preparation of TMSCCl3 in good yield (70 %) and excellent purity. Compounds of the type NBu4X [X=Ph3SiF2 (TBAT), F (tetrabutylammonium fluoride, TBAF), OAc, Cl and Br] act as catalytic promoters for 1,4-additions t... Read More about 1,4-addition of TMSCCl3to nitroalkenes: efficient reaction conditions and mechanistic understanding.

Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex (2014)
Journal Article
Lu, E., Cooper, O. J., McMaster, J., Tuna, F., McInnes, E. J., Lewis, W., …Liddle, S. T. (2014). Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex. Angewandte Chemie International Edition, 53(26), 6696-6700. https://doi.org/10.1002/anie.201403892

We report the uranium(VI) carbene imido oxo complex [U(BIPMTMS)(NMes)(O)(DMAP)2] (5, BIPMTMS=C(PPh2NSiMe3)2; Mes=2,4,6-Me3C6H2; DMAP=4-(dimethylamino)pyridine) which exhibits the unprecedented arrangement of three formal multiply bonded ligands to on... Read More about Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex.

Development of a redox-free mitsunobu reaction exploiting phosphine oxides as precursors to dioxyphosphoranes (2014)
Journal Article
Tang, X., Chapman, C., Whiting, M., & Denton, R. M. (in press). Development of a redox-free mitsunobu reaction exploiting phosphine oxides as precursors to dioxyphosphoranes. Chemical Communications, 50, https://doi.org/10.1039/C4CC02171A

The development of the first redox-free protocol for the Mitsunobu reaction is described. This has been achieved by exploiting triphenylphosphine oxide – the unwanted by-product in the conventional Mitsunobu reaction – as the precursor to the active... Read More about Development of a redox-free mitsunobu reaction exploiting phosphine oxides as precursors to dioxyphosphoranes.