Outputs (6)

Carboxylic acid functionalized spin-crossover iron(II) grids for tunable switching and hybrid electrode fabrication (2018)
Journal Article
Shiga, T., Sato, Y., Tachibana, M., Sato, H., Matsumoto, T., Sagayama, H., Kumai, R., Murakami, Y., Newton, G. N., & Oshio, H. (2018). Carboxylic acid functionalized spin-crossover iron(II) grids for tunable switching and hybrid electrode fabrication. Inorganic Chemistry, 57(22), 14013-14017. https://doi.org/10.1021/acs.inorgchem.8b01856

Two carboxyl-substituted iron(II) grids, one protonated, [Fe4(HL)4](BF4)4·4MeCN·AcOEt (1), and the other deprotonated, [Fe4(L)4]·DMSO·EtOH (2), where H2L = 4-{4,5-bis[6-(3,5-dimethylpyrazol-1-yl)pyrid-2-yl]-1H-imidazol-2-yl}benzoic acid, were synthes... Read More about Carboxylic acid functionalized spin-crossover iron(II) grids for tunable switching and hybrid electrode fabrication.

Cobalt complexes with redox-active anthraquinone-type ligands (2018)
Journal Article
Shiga, T., Kumamaru, R., Newton, G. N., & Oshio, H. (2018). Cobalt complexes with redox-active anthraquinone-type ligands. Dalton Transactions, 47(23), https://doi.org/10.1039/C8DT00586A

Three anthraquinone-type multidentate ligands, HL1-3 (HL = 2-R-1H-anthra[1,2-d]imidazole6,11-dione, HL1; R = (2-pyridyl), HL2; R = (4,6-dimethyl-2-pyridyl), HL3; R = (6-methoxy-2pyridyl)), were prepared, and their complexation behaviour were investig... Read More about Cobalt complexes with redox-active anthraquinone-type ligands.

Post-functionalization of a photoactive hybrid polyoxotungstate (2018)
Journal Article
Cameron, J. M., Fujimoto, S., Wei, R.-J., Newton, G. N., & Oshio, H. (in press). Post-functionalization of a photoactive hybrid polyoxotungstate. Dalton Transactions, https://doi.org/10.1039/C8DT01253A

A new post-functionalization strategy for hybrid polyoxometalate (POM) clusters is presented, whereby the electronic properties and visible-light driven oxidative reactivity of the POM core can be altered by controlled addition of transition metal io... Read More about Post-functionalization of a photoactive hybrid polyoxotungstate.

3D printable photochromic molecular materials for reversible information storage (2018)
Journal Article
Wales, D. J., Cao, Q., Kastner, K., Karjalainen, E., Newton, G. N., & Sans, V. (2018). 3D printable photochromic molecular materials for reversible information storage. Advanced Materials, 30(26), Article 1800159. https://doi.org/10.1002/adma.201800159

The formulation of advanced molecular materials with bespoke polymeric ionic liquid matrices that stabilize and solubilize hybrid organic-inorganic polyoxometalates and allow their processing by additive manufacturing, is effectively demonstrated. Th... Read More about 3D printable photochromic molecular materials for reversible information storage.

Pre-programmed self-assembly of polynuclear clusters (2018)
Journal Article
Shiga, T., Newton, G. N., & Oshio, H. (in press). Pre-programmed self-assembly of polynuclear clusters. Dalton Transactions, https://doi.org/10.1039/C8DT00822A

This perspective reviews our recent efforts towards the self-assembly of polynuclear clusters with ditopic and tritopic multidentate ligands HL1 (2-phenyl-4,5-bis{6-(3,5-dimethylpyrazol-1-yl)pyrid-2-yl}-1H-imidazole) and H2L2 (2,6-bis-[5-(2-pyridinyl... Read More about Pre-programmed self-assembly of polynuclear clusters.

Shining a light on the photo-sensitisation of organic-inorganic hybrid polyoxometalates (2018)
Journal Article
Cameron, J. M., Wales, D. J., & Newton, G. (in press). Shining a light on the photo-sensitisation of organic-inorganic hybrid polyoxometalates. Dalton Transactions, https://doi.org/10.1039/C8DT00400E

Finding new ways of using visible light (or, more specifically, solar irradiation) to drive commercially significant and/or challenging chemical processes is an ongoing research goal. Polyoxometalates (POMs) are discrete, metal-oxide clusters which a... Read More about Shining a light on the photo-sensitisation of organic-inorganic hybrid polyoxometalates.