Catalytic and kinetic investigation into 4-dimethylamino pyridine/1,3-diphenyl thiourea catalyzed synthesis of chloromethyl ethylene carbonate under pure CO₂ and simulated flue gas conditions
(2024)
Journal Article
Eton, U. O., Meredith, W., & Snape, C. E. (2025). Catalytic and kinetic investigation into 4-dimethylamino pyridine/1,3-diphenyl thiourea catalyzed synthesis of chloromethyl ethylene carbonate under pure CO₂ and simulated flue gas conditions. Fuel, 382(Part A), Article 133657. https://doi.org/10.1016/j.fuel.2024.133657
Synthesis of chloromethyl ethylene carbonate (CMEC) via CO2 cycloaddition to epichlorohydrin (ECH) has been investigated using a simple metal-free and halide-free catalyst comprising 4-dimethylamino pyridine (DMAP) and N–H type hydrogen bond donors (... Read More about Catalytic and kinetic investigation into 4-dimethylamino pyridine/1,3-diphenyl thiourea catalyzed synthesis of chloromethyl ethylene carbonate under pure CO₂ and simulated flue gas conditions.