Terminal uranium(V/VI) nitride activation of carbon dioxide and carbon disulfide: factors governing diverse and well-defined cleavage and redox reactions
(2017)
Journal Article
Cleaves, P. A., Kefalidis, C. E., Gardner, B. M., Tuna, F., McInnes, E. J., Lewis, W., …Liddle, S. T. (2017). Terminal uranium(V/VI) nitride activation of carbon dioxide and carbon disulfide: factors governing diverse and well-defined cleavage and redox reactions. Chemistry - A European Journal, 23(12), 2950-2959. https://doi.org/10.1002/chem.201605620
The reactivity of terminal uranium(V/VI) nitrides with CE2 (E=O, S) is presented. Well-defined C=E cleavage followed by zero-, one-, and two-electron redox events is observed. The uranium(V) nitride [U(TrenTIPS)(N)][K(B15C5)2] (1, TrenTIPS=N(CH2CH2NS... Read More about Terminal uranium(V/VI) nitride activation of carbon dioxide and carbon disulfide: factors governing diverse and well-defined cleavage and redox reactions.