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Synthesis of Highly Functionalized Bismacycles via Post-Transmetallation Modification of Aryboronic Acids (2023)
Journal Article
Sivanandan, S. T., Guiry, P. J., Owen, B., & Ball, L. (2023). Synthesis of Highly Functionalized Bismacycles via Post-Transmetallation Modification of Aryboronic Acids. Journal of Organic Chemistry, 88(14), 9730-9736. https://doi.org/10.1021/acs.joc.3c00361

Bismacycles featuring a sulfone-bridged scaffold have recently been developed as versatile and convenient electrophilic arylating agents. Here, we report that the exocyclic aryl group, which is ultimately transferred to a nucleophilic coupling partne... Read More about Synthesis of Highly Functionalized Bismacycles via Post-Transmetallation Modification of Aryboronic Acids.

Synthesis of Highly Functionalized Bismacycles via Post-Transmetallation Modification of Arylboronic Acids (2023)
Journal Article
Sivanandan, S. T., Owen, B., Guiry, P. J., & Ball, L. T. (2023). Synthesis of Highly Functionalized Bismacycles via Post-Transmetallation Modification of Arylboronic Acids. Journal of Organic Chemistry, 88(14), 9730–9736. https://doi.org/10.1021/acs.joc.3c00361

Bismacycles featuring a sulfone-bridged scaffold have recently been developed as versatile and convenient electrophilic arylating agents. Here, we report that the exocyclic aryl group, which is ultimately transferred to a nucleophilic coupling partne... Read More about Synthesis of Highly Functionalized Bismacycles via Post-Transmetallation Modification of Arylboronic Acids.

Visible Light‐Mediated Reactions of β‐Nitroalkenes (2022)
Journal Article
Sivanandan, S. T., Jesline, M. J., Nair, D. K., & Kumar, T. (2023). Visible Light‐Mediated Reactions of β‐Nitroalkenes. Asian Journal of Organic Chemistry, 12(1), Article e202200555. https://doi.org/10.1002/ajoc.202200555

Organic transformations using visible light-mediated photoredox reactions received significant attention in the past several years. Recently, nitroalkenes have emerged as an excellent coupling partner in the visible light-mediated photoredox reaction... Read More about Visible Light‐Mediated Reactions of β‐Nitroalkenes.