Visible Light‐Mediated Reactions of β‐Nitroalkenes

Sivanandan, Sudheesh T.; Jesline, Mukkath J.; Nair, Divya K.; Kumar, Tarun

Abstract

Organic transformations using visible light-mediated photoredox reactions received significant attention in the past several years. Recently, nitroalkenes have emerged as an excellent coupling partner in the visible light-mediated photoredox reactions. Due to the easy availability and diverse reactivity, several methodologies are reported on the photoredox-mediated reactions of nitroalkenes to attain different types of alkenes and heterocycles. Variety of reactions including denitrative coupling reactions, addition reactions and cycloadditions, etc. are reported. However, a review that focuses entirely on this topic has not appeared yet. Considering the synthetic potential of these class of reactions, we provide a summary of various methodologies developed for the reactions of nitroalkenes under visible light photoredox catalysis.

• Journal Article Type: Review
• Acceptance Date: Nov 1, 2022
• Online Publication Date: Nov 17, 2022
• Publication Date: 2023-01
• Deposit Date: Dec 20, 2022
• Publicly Available Date: Nov 18, 2023
• Journal: Asian Journal of Organic Chemistry
• Print ISSN: 2193-5807
• Electronic ISSN: 2193-5815
• Publisher: Wiley-VCH Verlag
• Peer Reviewed: Peer Reviewed
• Volume: 12
• Issue: 1
• Article Number: e202200555
• DOI: https://doi.org/10.1002/ajoc.202200555
• Public URL: https://nottingham-repository.worktribe.com/output/14304683
• Publisher URL: https://onlinelibrary.wiley.com/doi/full/10.1002/ajoc.202200555
• Additional Information: This is the peer reviewed version of the following article: S. T. Sivanandan, M. J. Jesline, D. K. Nair, T. Kumar, Asian J. Org. Chem. 2022, e202200555, which has been published in final form at https://doi.org/10.1002/ajoc.202200555.