All Outputs (2)

Encapsulation of reactive species within metal–organic cages (2025)
Journal Article
Bhattacharyya, S., Black, M. R., & Pilgrim, B. S. (2025). Encapsulation of reactive species within metal–organic cages. Chemical Science, https://doi.org/10.1039/d5sc02081f

Reactivity under confinement often differs greatly from reactivity in the bulk. Metal–organic cages (MOCs) are a class of discrete, solution-processable container molecules encompassing well-defined nanospaces, which can be rapidly constructed in mod... Read More about Encapsulation of reactive species within metal–organic cages.

Structural Transformations of Metal-Organic Cages through Tetrazine-Alkene Reactivity (2024)
Journal Article
Black, M. R., Bhattacharyya, S., Argent, S. P., & Pilgrim, B. S. (2024). Structural Transformations of Metal-Organic Cages through Tetrazine-Alkene Reactivity. Journal of the American Chemical Society, 146(41), 28233-28241. https://doi.org/10.1021/jacs.4c08591

The assembly of metal-organic cages is governed by metal ion coordination preferences and the geometries of the typically rigid and planar precursor ligands. PdnL2n cages are among the most structurally diverse, with subtle differences in the metal-l... Read More about Structural Transformations of Metal-Organic Cages through Tetrazine-Alkene Reactivity.