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Selective Photocatalytic Reduction of CO2 to CH4 over NU-1000 Metal-Organic Frameworks (2024)
Preprint / Working Paper
Korhonen, P., Thangamuthu, M., Castaldelli, E., Diego-Lopez, A., Weilhard, A., Clowes, R., O'Shea, J., Laybourn, A., & Lanterna, A. Selective Photocatalytic Reduction of CO2 to CH4 over NU-1000 Metal-Organic Frameworks

CO2 adsorption and its subsequent utilization represent a promising avenue for mitigating climate change. The conver-sion of CO2 into valuable and useful products like carbon monoxide, methane, and methanol offers significant economic benefits. Howev... Read More about Selective Photocatalytic Reduction of CO2 to CH4 over NU-1000 Metal-Organic Frameworks.

Epitaxy of GaSe Coupled to Graphene: From In Situ Band Engineering to Photon Sensing (2024)
Journal Article
Bradford, J., Dewes, B. T., Shiffa, M., Cottam, N. D., Rahman, K., Cheng, T. S., Novikov, S. V., Makarovsky, O., O'Shea, J. N., Beton, P. H., Lara-Avila, S., Harknett, J., Greenaway, M. T., & Patanè, A. (2024). Epitaxy of GaSe Coupled to Graphene: From In Situ Band Engineering to Photon Sensing. Small, 20(40), Article 2404809. https://doi.org/10.1002/smll.202404809

2D semiconductors can drive advances in quantum science and technologies. However, they should be free of any contamination; also, the crystallographic ordering and coupling of adjacent layers and their electronic properties should be well‐controlled... Read More about Epitaxy of GaSe Coupled to Graphene: From In Situ Band Engineering to Photon Sensing.

Porphyrin-fused graphene nanoribbons (2024)
Journal Article
Chen, Q., Lodi, A., Zhang, H., Gee, A., Wang, H. I., Kong, F., Clarke, M., Edmondson, M., Hart, J., O’Shea, J. N., Stawski, W., Baugh, J., Narita, A., Saywell, A., Bonn, M., Müllen, K., Bogani, L., & Anderson, H. L. (2024). Porphyrin-fused graphene nanoribbons. Nature Chemistry, 16, 1133-1140. https://doi.org/10.1038/s41557-024-01477-1

Graphene nanoribbons (GNRs), nanometre-wide strips of graphene, are promising materials for fabricating electronic devices. Many GNRs have been reported, yet no scalable strategies are known for synthesizing GNRs with metal atoms and heteroaromatic u... Read More about Porphyrin-fused graphene nanoribbons.

Structure and chemical composition of the Mg electrode during cycling in a simple glyme electrolyte (2024)
Journal Article
Dimogiannis, K., Sankowski, A., Holc, C., Parmenter, C. D., Newton, G. N., Walsh, D. A., …Johnson, L. R. (2024). Structure and chemical composition of the Mg electrode during cycling in a simple glyme electrolyte. Energy Storage Materials, 67, Article 103280. https://doi.org/10.1016/j.ensm.2024.103280

The volumetric energy density of magnesium exceeds that of lithium, making magnesium batteries particularly promising for next-generation energy storage. However, electrochemical cycling of magnesium electrodes in common battery electrolytes is coulo... Read More about Structure and chemical composition of the Mg electrode during cycling in a simple glyme electrolyte.

Template‐Directed Synthesis of Strained meso‐meso‐Linked Porphyrin Nanorings (2024)
Journal Article
Van Raden, J. M., Deng, J., Gotfredsen, H., Hergenhahn, J., Clarke, M., Edmondson, M., …Anderson, H. L. (2024). Template‐Directed Synthesis of Strained meso‐meso‐Linked Porphyrin Nanorings. Angewandte Chemie International Edition, Article e202400103. https://doi.org/10.1002/anie.202400103

Strained macrocycles display interesting properties, such as conformational rigidity, often resulting in enhance π‐conjugation or enhanced affinity for non‐covalent guest binding, yet they can be difficult to synthesize. Here we use computational mod... Read More about Template‐Directed Synthesis of Strained meso‐meso‐Linked Porphyrin Nanorings.