All Outputs (4)

Functionalization of Carbon Surfaces Tunes the Redox Stability of Polyoxometalate@Carbon Electrodes (2020)
Journal Article
Mughal, N. S., Walsh, D. A., & Newton, G. N. (2020). Functionalization of Carbon Surfaces Tunes the Redox Stability of Polyoxometalate@Carbon Electrodes. ACS Applied Energy Materials, 3(12), 12308-12315. https://doi.org/10.1021/acsaem.0c02360

The use of redox-active polyoxometalates (POMs) offers unique opportunities for the development of advanced functional materials, but the use of such systems is often limited by their instability in operando. To enhance the functional stability of PO... Read More about Functionalization of Carbon Surfaces Tunes the Redox Stability of Polyoxometalate@Carbon Electrodes.

Transition metal decorated soft nanomaterials through modular self-assembly of an asymmetric hybrid polyoxometalate (2020)
Journal Article
Hampson, E., Cameron, J. M., Watts, J. A., & Newton, G. N. (2020). Transition metal decorated soft nanomaterials through modular self-assembly of an asymmetric hybrid polyoxometalate. Chemical Communications, 56, 8237-8240. https://doi.org/10.1039/d0cc03554h

An asymmetrically functionalised Wells–Dawson organic–inorganic hybrid polyoxometalate has been post-functionalised by Pt2+ coordination, and demonstrates self-assembly into surface-decorated micellar nanostructures. This multifunctional hybrid mater... Read More about Transition metal decorated soft nanomaterials through modular self-assembly of an asymmetric hybrid polyoxometalate.

Redox‐Active Hybrid Polyoxometalate‐Stabilised Gold Nanoparticles (2020)
Journal Article
Martin, C., Kastner, K., Cameron, J. M., Hampson, E., Alves Fernandes, J., Gibson, E. K., …Newton, G. N. (2020). Redox‐Active Hybrid Polyoxometalate‐Stabilised Gold Nanoparticles. Angewandte Chemie International Edition, 59(34), 14331-14335. https://doi.org/10.1002/anie.202005629

We report the design and preparation of multifunctional hybrid nanomaterials through the stabilization of gold nanoparticles with thiol‐functionalised hybrid organic–inorganic polyoxometalates (POMs). The covalent attachment of the hybrid POM forms n... Read More about Redox‐Active Hybrid Polyoxometalate‐Stabilised Gold Nanoparticles.

Heteroleptic iron(ii) complexes with naphthoquinone-type ligands (2020)
Journal Article
Shiga, T., Kumamaru, R., Newton, G. N., & Oshio, H. (2020). Heteroleptic iron(ii) complexes with naphthoquinone-type ligands. Dalton Transactions, 49(5), 1485-1491. https://doi.org/10.1039/c9dt03946e

Heteroleptic iron complexes with a naphthoquinone-type ligand, 2-(pyridin-2-yl)-1H-naphtho[2,3-d]imidazole-4,9-dione (HL), were synthesized, and their structures and magnetic properties were investigated. Two spin-crossover complexes, [Fe(L)2(L1)] (1... Read More about Heteroleptic iron(ii) complexes with naphthoquinone-type ligands.