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Redox‐Active Hybrid Polyoxometalate‐Stabilised Gold Nanoparticles

Martin, Carmen; Kastner, Katharina; Cameron, Jamie M.; Hampson, Elizabeth; Alves Fernandes, Jesum; Gibson, Emma K.; Walsh, Darren A.; Sans, Victor; Newton, Graham N.

Authors

Carmen Martin

Katharina Kastner

Elizabeth Hampson

Emma K. Gibson

Victor Sans



Abstract

We report the design and preparation of multifunctional hybrid nanomaterials through the stabilization of gold nanoparticles with thiol‐functionalised hybrid organic–inorganic polyoxometalates (POMs). The covalent attachment of the hybrid POM forms new nanocomposites that are stable at temperatures and pH values which destroy analogous electrostatically functionalised nanocomposites. Photoelectrochemical analysis revealed the unique photochemical and redox properties of these systems.

Citation

Martin, C., Kastner, K., Cameron, J. M., Hampson, E., Alves Fernandes, J., Gibson, E. K., …Newton, G. N. (2020). Redox‐Active Hybrid Polyoxometalate‐Stabilised Gold Nanoparticles. Angewandte Chemie International Edition, 59(34), 14331-14335. https://doi.org/10.1002/anie.202005629

Journal Article Type Article
Acceptance Date May 20, 2020
Online Publication Date May 20, 2020
Publication Date Aug 17, 2020
Deposit Date Jul 1, 2020
Publicly Available Date Jul 2, 2020
Journal Angewandte Chemie International Edition
Print ISSN 1433-7851
Electronic ISSN 1521-3773
Publisher Wiley
Peer Reviewed Peer Reviewed
Volume 59
Issue 34
Pages 14331-14335
DOI https://doi.org/10.1002/anie.202005629
Keywords General Chemistry; Catalysis
Public URL https://nottingham-repository.worktribe.com/output/4743019
Publisher URL https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202005629

Files

anie.202005629 (1.6 Mb)
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Publisher Licence URL
http://creativecommons.org/licenses/by/4.0/





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