Carmen Martin
Redox‐Active Hybrid Polyoxometalate‐Stabilised Gold Nanoparticles
Martin, Carmen; Kastner, Katharina; Cameron, Jamie M.; Hampson, Elizabeth; Alves Fernandes, Jesum; Gibson, Emma K.; Walsh, Darren A.; Sans, Victor; Newton, Graham N.
Authors
Katharina Kastner
Jamie M. Cameron
Elizabeth Hampson
Dr JESUM ALVES FERNANDES JESUM.ALVESFERNANDES@NOTTINGHAM.AC.UK
Associate Professor
Emma K. Gibson
DARREN WALSH DARREN.WALSH@NOTTINGHAM.AC.UK
Professor of Chemistry
Victor Sans
GRAHAM NEWTON GRAHAM.NEWTON@NOTTINGHAM.AC.UK
Associate Professor
Abstract
We report the design and preparation of multifunctional hybrid nanomaterials through the stabilization of gold nanoparticles with thiol‐functionalised hybrid organic–inorganic polyoxometalates (POMs). The covalent attachment of the hybrid POM forms new nanocomposites that are stable at temperatures and pH values which destroy analogous electrostatically functionalised nanocomposites. Photoelectrochemical analysis revealed the unique photochemical and redox properties of these systems.
Citation
Martin, C., Kastner, K., Cameron, J. M., Hampson, E., Alves Fernandes, J., Gibson, E. K., …Newton, G. N. (2020). Redox‐Active Hybrid Polyoxometalate‐Stabilised Gold Nanoparticles. Angewandte Chemie International Edition, 59(34), 14331-14335. https://doi.org/10.1002/anie.202005629
Journal Article Type | Article |
---|---|
Acceptance Date | May 20, 2020 |
Online Publication Date | May 20, 2020 |
Publication Date | Aug 17, 2020 |
Deposit Date | Jul 1, 2020 |
Publicly Available Date | Jul 2, 2020 |
Journal | Angewandte Chemie International Edition |
Print ISSN | 1433-7851 |
Electronic ISSN | 1521-3773 |
Publisher | Wiley |
Peer Reviewed | Peer Reviewed |
Volume | 59 |
Issue | 34 |
Pages | 14331-14335 |
DOI | https://doi.org/10.1002/anie.202005629 |
Keywords | General Chemistry; Catalysis |
Public URL | https://nottingham-repository.worktribe.com/output/4743019 |
Publisher URL | https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202005629 |
Files
anie.202005629
(1.6 Mb)
PDF
Publisher Licence URL
https://creativecommons.org/licenses/by/4.0/
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