All Outputs (34)

Dynamic behavior of polymers (2024)
Book Chapter
Siviour, C. R., & De Focatiis, D. S. (2024). Dynamic behavior of polymers. In Dynamic Behavior of Materials: Fundamentals, Material Models, and Microstructure Effects (553-595). Elsevier. https://doi.org/10.1016/b978-0-323-99153-7.00013-x

Measuring, understanding, and modeling the high strain rate properties of polymers are of importance in a wide range of applications. These properties also give unique insight into the processes governing polymer deformation. Compared to metals, howe... Read More about Dynamic behavior of polymers.

Development of Deproteinized Natural Rubber Latex Foam for Seat Cushions (2023)
Journal Article
Ramli, R., Chai, A. B., Kamaruddin, S., Ho, J. H., & De Focatiis, D. S. (2023). Development of Deproteinized Natural Rubber Latex Foam for Seat Cushions. Key Engineering Materials, 962, 29-37. https://doi.org/10.4028/p-hwlt4p

In the transportation industry, seat cushions are crucial since they are directly responsible for the comfort and safety of the occupant. In this study, recently developed deproteinized natural rubber (DPNR) latex foam is used to make seat cushions f... Read More about Development of Deproteinized Natural Rubber Latex Foam for Seat Cushions.

Compressive Stress-Strain and Rebound Resilience Properties of Deproteinized Natural Rubber Latex Foam (2023)
Journal Article
Ramli, R., Chai, A. B., Kamaruddin, S., Ho, J. H., & De Focatiis, D. S. (2023). Compressive Stress-Strain and Rebound Resilience Properties of Deproteinized Natural Rubber Latex Foam. Key Engineering Materials, 962, 39-44. https://doi.org/10.4028/p-a5zmst

Deproteinized natural rubber (DPNR) latex is a modified version of natural rubber (NR) latex that is hypoallergenic and odorless when used in products. However, due to the lack of studies in this field, there are relatively few DPNR latex foam produc... Read More about Compressive Stress-Strain and Rebound Resilience Properties of Deproteinized Natural Rubber Latex Foam.

Effects of oil palm trunk biochar on the thermal stability and acoustic properties of specialty natural rubber latex foam (2023)
Journal Article
Ramli, R., Chai, A. B., Kamaruddin, S., Ho, J. H., Mohd. Rasdi, F. R., De Focatiis, D. S. A., …Bachmann, R. T. (2023). Effects of oil palm trunk biochar on the thermal stability and acoustic properties of specialty natural rubber latex foam. Journal of Rubber Research, 26(1), 1-15. https://doi.org/10.1007/s42464-023-00193-8

Specialty natural rubber (SpNR) latex foam is a natural-based acoustic foam material, that can substitute conventional synthetic foams to control noise pollution in buildings and in the transportation industry. However, the thermal stability of SpNR... Read More about Effects of oil palm trunk biochar on the thermal stability and acoustic properties of specialty natural rubber latex foam.

Anisotropic swelling of rubber: extension of the Flory theory (2022)
Journal Article
Fernandes, V. A., & De Focatiis, D. S. A. (2022). Anisotropic swelling of rubber: extension of the Flory theory. Journal of Rubber Research, https://doi.org/10.1007/s42464-022-00183-2

The anisotropy of the swelling of rubber is examined both theoretically and experimentally. The Flory theory is extended to account for anisotropic swelling, allowing the determination of the average molecular weight between cross-links for rubber wi... Read More about Anisotropic swelling of rubber: extension of the Flory theory.

The acoustic properties of latex foam made from deproteinized natural rubber latex and epoxidized natural rubber latex (2022)
Journal Article
Ramli, R., Chai, A. B., Kamaruddin, S., Ho, J. H., Rasdi, F. R. M., & De Focatiis, D. S. A. (2022). The acoustic properties of latex foam made from deproteinized natural rubber latex and epoxidized natural rubber latex. Journal of Rubber Research, 25(4), 321-336. https://doi.org/10.1007/s42464-022-00178-z

Acoustic foam materials are used to control noise pollution in a wide range of applications, including buildings and the transportation industry. This study explores the feasibility of replacing conventional acoustic foam made of synthetic material w... Read More about The acoustic properties of latex foam made from deproteinized natural rubber latex and epoxidized natural rubber latex.

Sustainable ABA triblock methacrylate copolymers incorporating both high and low Tg terpene-derived monomers (2022)
Journal Article
Atkinson, R. L., Elsmore, M., Smith, S., Reynolds-Green, M., Topham, P. D., Toolan, D. T., …Howdle, S. M. (2022). Sustainable ABA triblock methacrylate copolymers incorporating both high and low Tg terpene-derived monomers. European Polymer Journal, 179, Article 11567. https://doi.org/10.1016/j.eurpolymj.2022.111567

We report the synthesis of novel terpene-based monomers: nopinyl acrylate and methacrylate, from naturally abundant β-pinene. A very high Tg value was observed for poly(nopinyl methacrylate) when synthesised by free radical polymerisation, and well-d... Read More about Sustainable ABA triblock methacrylate copolymers incorporating both high and low Tg terpene-derived monomers.

Biomimetic folding of triangular deployable membranes (2022)
Journal Article
Tang, Y., Beccarelli, P., Guo, H., Liu, R., De Focatiis, D., & Deng, Z. (2022). Biomimetic folding of triangular deployable membranes. Bioinspiration and Biomimetics, 17(6), Article 066002. https://doi.org/10.1088/1748-3190/ac7fd3

Deployable membranes are being increasingly applied in numerous space projects owing to their light weight, small stowage volume and capacity for use at large scales. The geometric design of biomimetic folding is studied to design crease patterns for... Read More about Biomimetic folding of triangular deployable membranes.

Exploiting Generative Design for Multi-Material Inkjet 3D Printed Cell Instructive, Bacterial Biofilm Resistant Composites (2022)
Preprint / Working Paper
he, Y., Begines, B., Trindade, G., Abdi, M., dubern, J., Prina, E., …Wildman, R. Exploiting Generative Design for Multi-Material Inkjet 3D Printed Cell Instructive, Bacterial Biofilm Resistant Composites

As our understanding of disease grows, it is becoming established that treatment needs to be personalized and targeted to the needs of the individual. In this paper we show that multi-material inkjet-based 3D printing, when backed with generative des... Read More about Exploiting Generative Design for Multi-Material Inkjet 3D Printed Cell Instructive, Bacterial Biofilm Resistant Composites.

Sustainable terpene triblock copolymers with tuneable properties for pressure sensitive adhesive applications (2022)
Journal Article
Elsmore, M., Atkinson, R., Irvine, D., Howdle, S., & De Focatiis, D. (2022). Sustainable terpene triblock copolymers with tuneable properties for pressure sensitive adhesive applications. Polymer Testing, 109, Article 107530. https://doi.org/10.1016/j.polymertesting.2022.107530

A series of triblock copolymers in a hard-soft-hard block configuration with varying hard block α-pinene methacrylate content and molecular weight and butyl acrylate soft segment have been synthesised and investigated for viability in pressure sensit... Read More about Sustainable terpene triblock copolymers with tuneable properties for pressure sensitive adhesive applications.

Characterizing friction for fiber reinforced composites manufacturing: Method development and effect of process parameters (2022)
Journal Article
Das, A., Choong, G. Y. H., Dillard, D. A., De Focatiis, D. S. A., & Bortner, M. J. (2022). Characterizing friction for fiber reinforced composites manufacturing: Method development and effect of process parameters. Composites Part B: Engineering, 236, Article 109777. https://doi.org/10.1016/j.compositesb.2022.109777

In automated layup manufacturing processes of fiber-reinforced polymer composites, the quality of the manufactured part is strongly dependent on frictional behavior. Improper control of frictional forces can lead to defect formation. Frictional slidi... Read More about Characterizing friction for fiber reinforced composites manufacturing: Method development and effect of process parameters.

Preparation and characterization of speciality natural rubber latex concentrate (2022)
Journal Article
Ramli, R., Bao, C. A., Hou, J. H., Kamaruddin, S., Rasdi, F. R. M., & De Focatiis, D. S. A. (2022). Preparation and characterization of speciality natural rubber latex concentrate. Rubber Chemistry and Technology, 95(1), 101-118. https://doi.org/10.5254/RCT.21.79945

Conventionally, specialty natural rubber (SpNR) latex, namely deproteinised natural rubber (DPNR) latex and epoxidized natural rubber (ENR) latex, are prepared from low ammonia latex (LATZ) causing high material cost. To address this issue, the objec... Read More about Preparation and characterization of speciality natural rubber latex concentrate.

Specialty natural rubber latex foam: foamability study and fabrication process (2021)
Journal Article
Ramli, R., Chai, A. B., Ho, J. H., Kamaruddin, S., Rasdi, F. R. M., & De Focatiis, D. S. A. (2022). Specialty natural rubber latex foam: foamability study and fabrication process. Rubber Chemistry and Technology, 95(3), 492-513. https://doi.org/10.5254/rct.21.78938

Specialty natural rubber (SpNR) latex namely deproteinized natural rubber (DPNR) latex and epoxidized natural rubber (ENR) latex have been produced to meet specific product’s requirements. However, SpNR is normally used in the form of block rubber to... Read More about Specialty natural rubber latex foam: foamability study and fabrication process.

Development of latex foam pillows from deproteinized natural rubber latex (2021)
Journal Article
Ramli, R., Chai, A. B., Kamaruddin, S., Ho, J. H., Mohd. Rasdi, F. R., & De Focatiis, D. S. A. (2021). Development of latex foam pillows from deproteinized natural rubber latex. Journal of Rubber Research, 24(4), 615-630. https://doi.org/10.1007/s42464-021-00130-7

Currently there is significant demand for pillows with improved pressure-relief features made from natural materials, alternatives to petrochemical-based foams. In order to meet the requirements, this study's approach is to develop latex foam pillows... Read More about Development of latex foam pillows from deproteinized natural rubber latex.

RAFT polymerisation of renewable terpene (meth)acrylates and the convergent synthesis of methacrylate-acrylate-methacrylate triblock copolymers (2021)
Journal Article
Atkinson, R. L., Monaghan, O., Elsmore, M. T., Topham, P. D., Toolan, D. T. W., Derry, M. J., …Howdle, S. M. (2021). RAFT polymerisation of renewable terpene (meth)acrylates and the convergent synthesis of methacrylate-acrylate-methacrylate triblock copolymers. Polymer Chemistry, 12(21), 3177-3189. https://doi.org/10.1039/d1py00326g

Terpenes are ideal candidates for sustainable polymer feedstocks, due to their natural abundance and availability from existing waste streams. Previously, we have shown that a range of terpene(meth)acrylate monomers can be synthesised from the most c... Read More about RAFT polymerisation of renewable terpene (meth)acrylates and the convergent synthesis of methacrylate-acrylate-methacrylate triblock copolymers.

Analysis of contact area in a continuous application-and-peel test method for prepreg tack (2021)
Journal Article
Choong, G., Endruweit, A., & De Focatiis, D. (2021). Analysis of contact area in a continuous application-and-peel test method for prepreg tack. International Journal of Adhesion and Adhesives, 107, Article 102849. https://doi.org/10.1016/j.ijadhadh.2021.102849

The relationship between prepreg tack and the degree of intimate contact (DoIC) between prepreg and a rigid substrate was explored in the context of a continuous application-and-peel test method. Tack for a unidirectional prepreg tape was characteris... Read More about Analysis of contact area in a continuous application-and-peel test method for prepreg tack.

Combined roles of temperature and humidity on cure of a silicone elastomer (2020)
Journal Article
Elsmore, M. T., & De Focatiis, D. S. (2021). Combined roles of temperature and humidity on cure of a silicone elastomer. Polymer Testing, 93, 106967. https://doi.org/10.1016/j.polymertesting.2020.106967

A study of the cure kinetics of a one-part water-scavenging silicone elastomer was carried out under conditions of controlled humidity and temperature using rectangular bars subjected to oscillatory torsional shear. Characteristic cure times were obt... Read More about Combined roles of temperature and humidity on cure of a silicone elastomer.

Modeling non-linear rheology of PLLA: comparison of Giesekus and Rolie-Poly constitutive models (2020)
Journal Article
Stępień, M., Choong, G. Y., De Focatiis, D. S., & Figiel, Ł. (2020). Modeling non-linear rheology of PLLA: comparison of Giesekus and Rolie-Poly constitutive models. International Journal of Biobased Plastics, 2(1), 13-28. https://doi.org/10.1080/24759651.2020.1808367

Rheological models for biobased plastics can assist in predicting optimum processing parameters in industrial forming processes for biobased plastics and their composites such as film blowing, or injection stretch-blow molding in the packaging indust... Read More about Modeling non-linear rheology of PLLA: comparison of Giesekus and Rolie-Poly constitutive models.

A phenomenological constitutive model for the viscoelastic deformation of elastomers (2020)
Journal Article
Annarasa, V., Popov, A. A., & De Focatiis, D. S. A. (2020). A phenomenological constitutive model for the viscoelastic deformation of elastomers. Mechanics of Time-Dependent Materials, https://doi.org/10.1007/s11043-020-09452-2

This study proposes a one-dimensional constitutive model for elastomeric materials based on recent observations regarding the separation of elastic and viscous contributions in uniaxial cyclic tensile experiments on EPDM rubber. The focus is on captu... Read More about A phenomenological constitutive model for the viscoelastic deformation of elastomers.

Intrinsic dependence of ice adhesion strength on surface roughness (2020)
Journal Article
Memon, H., Liu, J., De Focatiis, D. S., Choi, K.-S., & Hou, X. (2020). Intrinsic dependence of ice adhesion strength on surface roughness. Surface and Coatings Technology, 385, Article 125382. https://doi.org/10.1016/j.surfcoat.2020.125382

The roles of surface roughness on icephobicity including ice adhesion strength have been long debated in icephobicity studies. However, the direct/systematic influence of surface roughness on ice adhesion strength while keeping other surface characte... Read More about Intrinsic dependence of ice adhesion strength on surface roughness.