All Outputs (2)

d10s2 Post-Transition Metal Anions: Identifying and Analyzing Their Dual-Mode Lewis Basicity (2025)
Journal Article
Seymour, J. M., Gousseva, E., Parker, L. G., Towers Tompkins, F. K., Fogarty, R. M., Frankemoelle, L., Rowe, R., Clarke, C. J., Duncan, D. A., Palgrave, R. G., Bennett, R. A., Hunt, P. A., & Lovelock, K. R. J. (in press). d10s2 Post-Transition Metal Anions: Identifying and Analyzing Their Dual-Mode Lewis Basicity. Journal of Physical Chemistry Letters, 16(11), 2831-2836. https://doi.org/10.1021/acs.jpclett.4c03649

Liquid-phase d10s2 post-transition metal anions, such as [SnCl3]−, appear in a range of applications with a focus on catalysis and material preparation. However, little is known about their electronic structure and how it relates to reactivity. Using... Read More about d10s2 Post-Transition Metal Anions: Identifying and Analyzing Their Dual-Mode Lewis Basicity.

Complex Self-Organization in n-Alkylammonium Sulfobetaine Zwitterions with High Thermal Stabilities and High Expansion Coefficients (2025)
Journal Article
Lange, A., Holtzheimer, L., Clarke, C., Thünemann, A. F., & Taubert, A. (2025). Complex Self-Organization in n-Alkylammonium Sulfobetaine Zwitterions with High Thermal Stabilities and High Expansion Coefficients. Langmuir, 41(7), 4422-4434. https://doi.org/10.1021/acs.langmuir.4c02892

Sulfobetaine zwitterions made from n-alkyl dimethylamines and butanesultone yield a series of n-alkylammonium sulfobetaine zwitterions with complex self-organization behavior. The compounds are thermally quite stable and the length of the alkyl chain... Read More about Complex Self-Organization in n-Alkylammonium Sulfobetaine Zwitterions with High Thermal Stabilities and High Expansion Coefficients.