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All Outputs (17)

Continuous flow synthesis of MOF UTSA-16(Zn), mixed-metal and magnetic composites for CO2 capture – toward scalable manufacture (2024)
Journal Article
Woodliffe, J. L., Molinar-Díaz, J., Clowes, R., Hussein, O. H., Lester, E., Ferrari, R., Ahmed, I., & Laybourn, A. (2024). Continuous flow synthesis of MOF UTSA-16(Zn), mixed-metal and magnetic composites for CO2 capture – toward scalable manufacture. Journal of Environmental Chemical Engineering, 12(6), Article 114167. https://doi.org/10.1016/j.jece.2024.114167

UTSA-16(Zn) is a zinc and citrate-based metal-organic framework (MOF) which has shown highly promising performance for CO2 capture. However, the transition of this MOF to industrial application has been hindered as a scalable synthesis method has not... Read More about Continuous flow synthesis of MOF UTSA-16(Zn), mixed-metal and magnetic composites for CO2 capture – toward scalable manufacture.

Selective Photocatalytic Reduction of CO2 to CH4 over NU-1000 Metal-Organic Frameworks (2024)
Preprint / Working Paper
Korhonen, P., Thangamuthu, M., Castaldelli, E., Diego-Lopez, A., Weilhard, A., Clowes, R., O'Shea, J., Laybourn, A., & Lanterna, A. Selective Photocatalytic Reduction of CO2 to CH4 over NU-1000 Metal-Organic Frameworks

CO2 adsorption and its subsequent utilization represent a promising avenue for mitigating climate change. The conver-sion of CO2 into valuable and useful products like carbon monoxide, methane, and methanol offers significant economic benefits. Howev... Read More about Selective Photocatalytic Reduction of CO2 to CH4 over NU-1000 Metal-Organic Frameworks.

Rapid microwave synthesis of sustainable magnetic framework composites of UTSA-16(Zn) with Fe3O4 nanoparticles for efficient CO2 capture (2023)
Journal Article
Woodliffe, J. L., Johnston, A.-L., Fay, M., Ferrari, R., Gomes, R. L., Lester, E., …Laybourn, A. (2023). Rapid microwave synthesis of sustainable magnetic framework composites of UTSA-16(Zn) with Fe3O4 nanoparticles for efficient CO2 capture. Materials Advances, 4(11), 5838-5849. https://doi.org/10.1039/D3MA00351E

Metal-organic frameworks (MOFs) have shown excellent potential for carbon dioxide capture applications due to their high sorption capacities and selectivities. However, MOFs are typically thermally insulating, and so thermal CO2 regeneration is chall... Read More about Rapid microwave synthesis of sustainable magnetic framework composites of UTSA-16(Zn) with Fe3O4 nanoparticles for efficient CO2 capture.

Green Synthesis of Reticular Materials (2023)
Journal Article
Desai, A. V., Lizundia, E., Laybourn, A., Rainer, D. N., Armstrong, A. R., Morris, R. E., …Ettlinger, R. (2023). Green Synthesis of Reticular Materials. Advanced Functional Materials, Article 2304660. https://doi.org/10.1002/adfm.202304660

To help ensure a prosperous future on Earth for coming generations, academia and industry need to transform the way they plan and carry out the synthesis of novel materials to make them more environmentally sustainable. In particular, the field of re... Read More about Green Synthesis of Reticular Materials.

A lithium-air battery and gas handling system demonstrator (2023)
Journal Article
Jordan, J. W., Vailaya, G., Holc, C., Jenkins, M., McNulty, R. C., Puscalau, C., …Johnson, L. R. (2024). A lithium-air battery and gas handling system demonstrator. Faraday Discussions, 248, 381-391. https://doi.org/10.1039/d3fd00137g

The lithium-air (Li-air) battery offers one of the highest practical specific energy densities of any battery system at >400 W h kgsystem−1. The practical cell is expected to operate in air, which is flowed into the positive porous electrode where it... Read More about A lithium-air battery and gas handling system demonstrator.

Rapid synthesis of magnetic microspheres and the development of new macro-micro hierarchically porous magnetic framework composites (2023)
Journal Article
Woodliffe, J. L., Molinar-Díaz, J., Islam, M. T., Stevens, L. A., Wadge, M. D., Rance, G. A., …Laybourn, A. (2023). Rapid synthesis of magnetic microspheres and the development of new macro-micro hierarchically porous magnetic framework composites. Journal of Materials Chemistry A, 11(27), 14705-14719. https://doi.org/10.1039/D3TA01927F

Magnetic framework composites (MFCs) are a highly interesting group of materials that contain both metal–organic frameworks (MOFs) and magnetic materials. Combining the unique benefits of MOFs (tuneable natures, high surface areas) with the advantage... Read More about Rapid synthesis of magnetic microspheres and the development of new macro-micro hierarchically porous magnetic framework composites.

Quid Pro Flow (2023)
Journal Article
Laybourn, A., Robertson, K., & Slater, A. G. (2023). Quid Pro Flow. Journal of the American Chemical Society, 145(8), 4355–4365. https://doi.org/10.1021/jacs.2c13670

How do you get into flow? We trained in flow chemistry during postdoctoral research and are now applying it in new areas: materials chemistry, crystallization, and supramolecular synthesis. Typically, when researchers think of “flow”, they are consid... Read More about Quid Pro Flow.

Electrocatalytic hydrogen evolution over micro and mesoporous cobalt metal-organic frameworks (2022)
Journal Article
Iqbal, B., Laybourn, A., O'Shea, J. N., Argent, S. P., & Zaheer, M. (2022). Electrocatalytic hydrogen evolution over micro and mesoporous cobalt metal-organic frameworks. Molecular Catalysis, 531, Article 112711. https://doi.org/10.1016/j.mcat.2022.112711

The development of water electrolysis devices is crucial for the sustainable production of green hydrogen fuel. However, the slow kinetics and high overpotential are key shortfalls for hydrogen production during the half-cell hydrogen evolution react... Read More about Electrocatalytic hydrogen evolution over micro and mesoporous cobalt metal-organic frameworks.

Size-controlled synthesis of spinel nickel ferrite nanorods by thermal decomposition of a bimetallic Fe/Ni-MOF (2021)
Journal Article
Iqbal, B., Laybourn, A., ul-Hamid, A., & Zaheer, M. (2021). Size-controlled synthesis of spinel nickel ferrite nanorods by thermal decomposition of a bimetallic Fe/Ni-MOF. Ceramics International, 47(9), 12433-12441. https://doi.org/10.1016/j.ceramint.2021.01.100

In this work, size-controlled synthesis of nickel ferrite nanoparticles was achieved by the calcination of a bimetallic (Fe/Ni) metal-organic framework (MOF). The bimetallic MOF (Fe2Ni-MIL-88B) itself was prepared by a two-step route. The first step... Read More about Size-controlled synthesis of spinel nickel ferrite nanorods by thermal decomposition of a bimetallic Fe/Ni-MOF.

Evaluating the purification and activation of metal-organic frameworks from a technical and circular economy perspective (2020)
Journal Article
Woodliffe, J. L., Ferrari, R. S., Ahmed, I., & Laybourn, A. (2020). Evaluating the purification and activation of metal-organic frameworks from a technical and circular economy perspective. Coordination Chemistry Reviews, 428, Article 213578. https://doi.org/10.1016/j.ccr.2020.213578

Metal-organic frameworks (MOFs) are highly porous materials consisting of metal ions or clusters linked by organic molecules. The high value of MOFs arises from the amount of empty space within their structure (up to 90%) and their tuneable structure... Read More about Evaluating the purification and activation of metal-organic frameworks from a technical and circular economy perspective.

Combining continuous flow oscillatory baffled reactors and microwave heating: Process intensification and accelerated synthesis of metal-organic frameworks (2018)
Journal Article
Laybourn, A., López-Fernández, A. M., Thomas-Hillman, I., Katrib, J., Lewis, W., Dodds, C., …Kingman, S. W. (2019). Combining continuous flow oscillatory baffled reactors and microwave heating: Process intensification and accelerated synthesis of metal-organic frameworks. Chemical Engineering Journal, 356, 170-177. https://doi.org/10.1016/j.cej.2018.09.011

We have constructed a continuous flow oscillatory baffled reactor (CF-OBR) equipped with a homogeneous and controllable microwave applicator in an entirely novel design. This affords a new route to chemical production incorporating many of the princi... Read More about Combining continuous flow oscillatory baffled reactors and microwave heating: Process intensification and accelerated synthesis of metal-organic frameworks.

Realising the environmental benefits of metal–organic frameworks: recent advances in microwave synthesis (2018)
Journal Article
Thomas-Hillman, I., Laybourn, A., Dodds, C., & Kingman, S. W. (2018). Realising the environmental benefits of metal–organic frameworks: recent advances in microwave synthesis. Journal of Materials Chemistry A, 6(25), 11564-11581. https://doi.org/10.1039/c8ta02919a

Metal–organic frameworks (MOFs) are a broad class of porous crystalline materials that show great potential for a wide-range of applications in areas such as energy and environmental sustainability. MOFscan show significant advantages in gas selectiv... Read More about Realising the environmental benefits of metal–organic frameworks: recent advances in microwave synthesis.

Metal-organic frameworks in seconds via selective microwave heating (2017)
Journal Article
Laybourn, A., Katrib, J., Ferrari-John, R. S., Morris, C. G., Yang, S., Udoudo, O., …Schröder, M. (2017). Metal-organic frameworks in seconds via selective microwave heating. Journal of Materials Chemistry A, 5(16), 7333-7338. https://doi.org/10.1039/C7TA01493G

© The Royal Society of Chemistry. Synthesis of metal-organic framework (MOF) materials via microwave heating often involves shorter reaction times and offers enhanced control of particle size compared to conventional heating. However, there is little... Read More about Metal-organic frameworks in seconds via selective microwave heating.

Understanding the electromagnetic interaction of metal organic framework reactants in aqueous solution at microwave frequencies (2016)
Journal Article
Laybourn, A., Katrib, J., Palade, P. A., Easun, T. L., Champness, N. R., Schröder, M., & Kingman, S. W. (2016). Understanding the electromagnetic interaction of metal organic framework reactants in aqueous solution at microwave frequencies. Physical Chemistry Chemical Physics, 18(7), https://doi.org/10.1039/C5CP05426E

Preparation of metal organic frameworks (MOFs) via microwave heating is becoming increasingly popular due to reduced reaction times and enhanced control of MOF particle size. However, there is little understanding about the detailed interaction of th... Read More about Understanding the electromagnetic interaction of metal organic framework reactants in aqueous solution at microwave frequencies.

Triazine-based graphitic carbon nitride: a two-dimensional semiconductor (2014)
Journal Article
Siller-Algara, G., Severin, N., Chong, S. Y., Björkman, T., Palgrave, R. G., Laybourn, A., …Bojdys, M. J. (2014). Triazine-based graphitic carbon nitride: a two-dimensional semiconductor. Angewandte Chemie International Edition, 53(29), https://doi.org/10.1002/anie.201402191

Graphitic carbon nitride has been predicted to be structurally analogous to carbon-only graphite, yet with an inherent bandgap. We have grown, for the first time, macroscopically large crystalline thin films of triazine-based, graphitic carbon nitrid... Read More about Triazine-based graphitic carbon nitride: a two-dimensional semiconductor.

Post-synthetic modification of conjugated microporous polymers (2013)
Journal Article
Ratvijitvech, T., Dawson, R., Laybourn, A., Khimyak, Y. Z., Adams, D. J., & Cooper, A. I. (2014). Post-synthetic modification of conjugated microporous polymers. Polymer, 55(1), 321-325. https://doi.org/10.1016/j.polymer.2013.06.004

Control over the surface functionality and microporosity in conjugated microporous polymers (CMPs) has been achieved by the post-synthetic modification of amines into amides of with different alkyl chains, one of which was chiral. The surface areas,... Read More about Post-synthetic modification of conjugated microporous polymers.