Carlo U. Perotto
A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases
Perotto, Carlo U.; Marshall, George; Jones, Graham J.; Lewis, William; McMaster, Jonathan; Schr�der, Martin
Authors
GEORGE MARSHALL GEORGE.MARSHALL@NOTTINGHAM.AC.UK
Senior Project Manager
Graham J. Jones
William Lewis
JONATHAN MCMASTER Jonathan.McMaster@nottingham.ac.uk
Professor of Chemistry
Martin Schr�der
Abstract
Ni(L1)Fe(tBuNC)4](PF6)2 is a robust NiIIFeII complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L1)Fe(tBuNC)4]+ is an unprecedented NiIFeII species that reproduces the electronic configuration of the Ni-L state of the [NiFe] hydrogenases.
Citation
Perotto, C. U., Marshall, G., Jones, G. J., Lewis, W., McMaster, J., & Schröder, M. (2015). A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases. Chemical Communications, 51, https://doi.org/10.1039/c5cc05881c
Journal Article Type | Article |
---|---|
Publication Date | Sep 30, 2015 |
Deposit Date | Nov 30, 2015 |
Publicly Available Date | Nov 30, 2015 |
Journal | Chemical Communications |
Print ISSN | 1359-7345 |
Electronic ISSN | 1364-548X |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 51 |
DOI | https://doi.org/10.1039/c5cc05881c |
Public URL | https://nottingham-repository.worktribe.com/output/760231 |
Publisher URL | http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC05881C#!divAbstract |
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