Skip to main content

Research Repository

Advanced Search

Critical assessment of the evidence for striped nanoparticles

Shankar, Sangaru Shiv; Stirling, Julian; Lekkas, Ioannis; Sweetman, Adam; Djuranovic, Predrag; Guo, Quanmin; Pauw, Brian; Granwehr, Josef; Lévy, Raphaël; Moriarty, Philip

Authors

Sangaru Shiv Shankar

Julian Stirling

Ioannis Lekkas

Adam Sweetman

Predrag Djuranovic

Quanmin Guo

Brian Pauw

Josef Granwehr

Raphaël Lévy



Abstract

There is now a significant body of literature which reports that stripes form in the ligand shell of suitably functionalised Au nanoparticles. This stripe morphology has been proposed to strongly affect the physicochemical and biochemical properties of the particles. We critique the published evidence for striped nanoparticles in detail, with a particular focus on the interpretation of scanning tunnelling microscopy (STM) data (as this is the only technique which ostensibly provides direct evidence for the presence of stripes). Through a combination of an exhaustive re-analysis of the original data, in addition to new experimental measurements of a simple control sample comprising entirely unfunctionalised particles, we show that all of the STM evidence for striped nanoparticles published to date can instead be explained by a combination of well-known instrumental artefacts, or by issues with data acquisition/analysis protocols. We also critically re-examine the evidence for the presence of ligand stripes which has been claimed to have been found from transmission electron microscopy, nuclear magnetic resonance spectroscopy, small angle neutron scattering experiments, and computer simulations. Although these data can indeed be interpreted in terms of stripe formation, we show that the reported results can alternatively be explained as arising from a combination of instrumental artefacts and inadequate data analysis techniques.

Journal Article Type Article
Publication Date Nov 14, 2014
Journal PLoS ONE
Electronic ISSN 1932-6203
Publisher Public Library of Science
Peer Reviewed Peer Reviewed
Volume 9
Issue 11
Article Number e108482
APA6 Citation Shankar, S. S., Stirling, J., Lekkas, I., Sweetman, A., Djuranovic, P., Guo, Q., …Moriarty, P. (2014). Critical assessment of the evidence for striped nanoparticles. PLoS ONE, 9(11), doi:10.1371/journal.pone.0108482
DOI https://doi.org/10.1371/journal.pone.0108482
Publisher URL http://journals.plos.org/plosone/article?id=10.1371/journal.pone.0108482
Copyright Statement Copyright information regarding this work can be found at the following address: http://creativecommons.org/licenses/by/4.0

Files

stirling_critical.pdf (8.2 Mb)
PDF

Copyright Statement
Copyright information regarding this work can be found at the following address: http://creativecommons.org/licenses/by/4.0





You might also like



Downloadable Citations

;