Understanding the reaction pathway of lithium borohydride-hydroxide-based multi-component systems for enhanced hydrogen storage

Munshi, Sweta; Walker, Gavin S.; Manickam, Kandavel; Hansen, Thomas; Dornheim, Martin; Grant, David M.

Abstract

Complex hydride-metal hydroxide multicomponent hydrogen storage systems have high potential for hydrogen storage because their dehydrogenation thermodynamics can be tuned while maintaining a high hydrogen storage capacity. Out of all the ratios explored using lithium borohydride and lithium hydroxide (LiBH4-xLiOH, x = 1, 3, 4), a particularly promising system is LiBH4-3LiOH with a maximum storage capacity of 7.47 wt%. Thermal and diffraction studies along with in situ neutron diffraction reveal new insights into the intermediate phases involved in the reaction pathway, enabling the identification of a detailed reaction schematic. The onset decomposition temperature was reduced to 220 °C for the hand-milled 1 : 3 system, releasing 6 wt% of H2 by 370 °C. Li3BO3 was the main decomposition product. Other than a small trace of water, no toxic gas release was detected along with the H2 release. Ball-milling showed improved reaction kinetics by releasing around 6 wt% between 200 and 260 °C in one step. The destabilization was achieved through the coupling reaction between Hδ− in [BH4]− and Hδ+ in [OH]−. Among all the catalysts investigated, the addition of 5 wt% NiCl2 led to further improvement in reaction kinetics. This resulted in a decrease in the onset decomposition temperature to 80 °C and released 6 wt% of H2 below 300 °C. The systems have exhibited improvements in kinetics and operational temperature, showing potential as a single use hydrogen storage material.

Citation

Munshi, S., Walker, G. S., Manickam, K., Hansen, T., Dornheim, M., & Grant, D. M. (2024). Understanding the reaction pathway of lithium borohydride-hydroxide-based multi-component systems for enhanced hydrogen storage. Journal of Materials Chemistry A, 12(41), 28326-28336. https://doi.org/10.1039/d4ta05368k

• Journal Article Type: Article
• Acceptance Date: Sep 10, 2024
• Online Publication Date: Sep 13, 2024
• Publication Date: Nov 7, 2024
• Deposit Date: Oct 24, 2024
• Publicly Available Date: Oct 28, 2024
• Journal: Journal of Materials Chemistry A
• Print ISSN: 2050-7488
• Electronic ISSN: 2050-7496
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 12
• Issue: 41
• Pages: 28326-28336
• DOI: https://doi.org/10.1039/d4ta05368k
• Public URL: https://nottingham-repository.worktribe.com/output/40000348