Inorganic Metal Thiocyanates

Cliffe, Matthew J.

Abstract

Metal thiocyanates were some of the first pseudohalide compounds to be discovered and adopt a diverse range of structures. This review describes the structures, properties, and syntheses of the known binary and ternary metal thiocyanates. It provides a categorization of their diverse structures and connects them to the structures of atomic inorganic materials. In addition to this description of characterized binary and ternary thiocyanates, this review summarizes the state of knowledge for all other binary metal thiocyanates. It concludes by highlighting opportunities for future materials development.

Citation

Cliffe, M. J. (2024). Inorganic Metal Thiocyanates. Inorganic Chemistry, 63(29), 13137-13156. https://doi.org/10.1021/acs.inorgchem.4c00920

• Journal Article Type: Review
• Acceptance Date: Jun 20, 2024
• Online Publication Date: Jul 9, 2024
• Publication Date: Jul 9, 2024
• Deposit Date: Jul 16, 2024
• Publicly Available Date: Jul 16, 2024
• Journal: Inorganic Chemistry
• Print ISSN: 0020-1669
• Electronic ISSN: 1520-510X
• Publisher: American Chemical Society
• Peer Reviewed: Peer Reviewed
• Volume: 63
• Issue: 29
• Pages: 13137-13156
• DOI: https://doi.org/10.1021/acs.inorgchem.4c00920
• Keywords: Chemical structure, Crystal structure, Inorganic carbon compounds, Metals, Phase transitions
• Public URL: https://nottingham-repository.worktribe.com/output/37158644
• Publisher URL: https://dx.doi.org/10.1021/acs.inorgchem.4c00920