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Suitability testing of selected wastes and natural substrates for permeable reactive barriers (PRBs)

Wantanaphong, Janthawan; Bailey, Elizabeth Helen; Mooney, Sacha Jon

Authors

Janthawan Wantanaphong

LIZ BAILEY LIZ.BAILEY@NOTTINGHAM.AC.UK
Professor of Environmental Geochemistry

SACHA MOONEY sacha.mooney@nottingham.ac.uk
Professor of Soil Physics



Abstract

Performance of barrier materials is important for the long-term success of permeable reactive barriers (PRBs). A number of selected wastes and natural materials were tested in batch experiments for their ability to remove heavy metals from synthetic groundwater. Two potential materials (clinoptilolite and calcified seaweed) were further investigated in column and elution experiments. Results showed that both materials have high metal removal (immobilization) (>95%) efficiencies. However, pore clogging as a consequence of mineral precipitation was recorded in a calcified seaweed column (size fraction 0.1-1.0 mm) after 7 months. Clogging was not observed in clinoptilolite columns. Elution tests showed some subsequent release of Cu, Cd and Zn in clinoptilolite and calcified seaweed columns eluted with acidic solution. Desorption of Cd and Zn was observed in a clinoptilolite column eluted with alkaline solution. No significant release of metals was observed in any of the columns eluted with a neutral pH fluid.

Journal Article Type Article
Publication Date Aug 29, 2005
Deposit Date Feb 3, 2020
Journal IAHS-AISH Publication
Print ISSN 0144-7815
Peer Reviewed Peer Reviewed
Issue 298
Pages 110-116
Public URL https://nottingham-repository.worktribe.com/output/3191831