Short-Range Ordering in Battery Electrode, the ‘Cation-Disordered’ Rocksalt Li1.25Nb0.25Mn0.5O2

Jones, Michael; Reeves, PhilipJ.; Seymour, Ieuan D.; Cliffe, Matthew J.; Dutton, Sia?n E.; Grey, Clare

Abstract

Cation order, with a local structure related to γ-LiFeO2, is observed in the nominally cation-disordered Li-excess rocksalt Li1.25Nb0.25Mn0.5O2via X-ray diffraction, neutron pair distribution function analysis, magnetic susceptibility and NMR spectroscopy. The correlation length of ordering depends on synthesis conditions and has implications for the electrochemistry of these phases.

Citation

Jones, M., Reeves, P., Seymour, I. D., Cliffe, M. J., Dutton, S. E., & Grey, C. (2019). Short-Range Ordering in Battery Electrode, the ‘Cation-Disordered’ Rocksalt Li1.25Nb0.25Mn0.5O2. Chemical Communications, 55(61), 9027-9030. https://doi.org/10.1039/C9CC04250D

• Journal Article Type: Article
• Acceptance Date: Jul 2, 2019
• Online Publication Date: Jul 4, 2019
• Publication Date: Aug 7, 2019
• Deposit Date: Aug 10, 2020
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 55
• Issue: 61
• Pages: 9027-9030
• DOI: https://doi.org/10.1039/C9CC04250D
• Public URL: https://nottingham-repository.worktribe.com/output/3020369
• Publisher URL: https://pubs.rsc.org/en/content/articlelanding/2019/CC/C9CC04250D#!divAbstract