Xiaohang Zhou
Electrochemical Performance of Screen-Printed Composite Coatings of Conducting Polymers and Carbon Nanotubes on Titanium Bipolar Plates in Aqueous Asymmetrical Supercapacitors
Zhou, Xiaohang; Chen, George Z.
Authors
Professor of Electrochemical Technologies GEORGE CHEN GEORGE.CHEN@NOTTINGHAM.AC.UK
Professor of Electrochemical Technologies
Abstract
Composites of conducting polymers (polypyrrole and polyaniline) with acid treated multi-walled carbon nanotubes were formulated into printable aqueous inks, with the aid of functional additives (benzethonium chloride as a surfactant with or without polyvinyl alcohol as a binder). The inks were screen-printed as fairly uniform coatings of various mass loading densities and areas (up to 75 mg·cm-2 and 100 cm2) on thin titanium plates (0.1 mm in thickness). These screen-printed plates were used to fabricate both unit cell and multi-cell stack of asymmetrical supercapacitors with screen-printed negative electrodes of activated carbon (pigment black) in aqueous electrolytes (3.0 mol·L-1 KCl or 1.0 mol·L-1 HCl). In particular, a three-cell stack with two bipolar Ti plates of 100 cm2 in screen-printed area was constructed, demonstrating promising technical specifications: 3.0 V in stack voltage, 1.29 ~ 1.83 F·cm-2 in electrode capacitance, 2.30 ~ 3.24 Wh·kg-1 in specific energy, and 1.04 kW·kg-1 in maximum specific power. Cyclic voltammetry, galvanostatic charging and discharging, and electrochemical impedance spectrometry were applied to study the composites, screen-printed coatings and individual and bipolarly stacked cells, assisted by optical and electron microscopy.
Journal Article Type | Article |
---|---|
Publication Date | Dec 3, 2012 |
Deposit Date | Jun 25, 2023 |
Journal | Journal of Electrochemistry |
Publisher | Chinese Electrochemical Society |
Peer Reviewed | Peer Reviewed |
Volume | 18 |
Issue | 5-6 |
Pages | 548-565 |
Public URL | https://nottingham-repository.worktribe.com/output/22186922 |
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