MATTHEW CLIFFE Matthew.Cliffe@nottingham.ac.uk
Associate Professor
Defect-dependent colossal negative thermal expansion in UiO-66(Hf) metal–organic framework
Cliffe, Matthew J.; Hill, Joshua A.; Murray, Claire A.; Coudert, Fran�ois-Xavier; Goodwin, Andrew L.
Authors
Joshua A. Hill
Claire A. Murray
Fran�ois-Xavier Coudert
Andrew L. Goodwin
Abstract
Thermally-densified hafnium terephthalate UiO-66(Hf) is shown to exhibit the strongest isotropic negative thermal expansion (NTE) effect yet reported for a metal–organic framework (MOF). Incorporation of correlated vacancy defects within the framework affects both the extent of thermal densification and the magnitude of NTE observed in the densified product. We thus demonstrate that defect inclusion can be used to tune systematically the physical behaviour of a MOF.
Citation
Cliffe, M. J., Hill, J. A., Murray, C. A., Coudert, F., & Goodwin, A. L. (2015). Defect-dependent colossal negative thermal expansion in UiO-66(Hf) metal–organic framework. Physical Chemistry Chemical Physics, 17(17), 11586-11592. https://doi.org/10.1039/c5cp01307k
Journal Article Type | Article |
---|---|
Acceptance Date | Mar 31, 2015 |
Online Publication Date | Apr 2, 2015 |
Publication Date | Apr 2, 2015 |
Deposit Date | Dec 20, 2018 |
Journal | Physical Chemistry Chemical Physics |
Print ISSN | 1463-9076 |
Electronic ISSN | 1463-9084 |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 17 |
Issue | 17 |
Pages | 11586-11592 |
DOI | https://doi.org/10.1039/c5cp01307k |
Public URL | https://nottingham-repository.worktribe.com/output/1431493 |
Publisher URL | https://pubs.rsc.org/en/Content/ArticleLanding/2015/CP/C5CP01307K#!divAbstract |
Related Public URLs | https://arxiv.org/abs/1503.01668 |
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