Defect-dependent colossal negative thermal expansion in UiO-66(Hf) metal–organic framework

Cliffe, Matthew J.; Hill, Joshua A.; Murray, Claire A.; Coudert, Fran�ois-Xavier; Goodwin, Andrew L.

Abstract

Thermally-densified hafnium terephthalate UiO-66(Hf) is shown to exhibit the strongest isotropic negative thermal expansion (NTE) effect yet reported for a metal–organic framework (MOF). Incorporation of correlated vacancy defects within the framework affects both the extent of thermal densification and the magnitude of NTE observed in the densified product. We thus demonstrate that defect inclusion can be used to tune systematically the physical behaviour of a MOF.

Citation

Cliffe, M. J., Hill, J. A., Murray, C. A., Coudert, F.-X., & Goodwin, A. L. (2015). Defect-dependent colossal negative thermal expansion in UiO-66(Hf) metal–organic framework. Physical Chemistry Chemical Physics, 17(17), 11586-11592. https://doi.org/10.1039/c5cp01307k

• Journal Article Type: Article
• Acceptance Date: Mar 31, 2015
• Online Publication Date: Apr 2, 2015
• Publication Date: Apr 2, 2015
• Deposit Date: Dec 20, 2018
• Journal: Physical Chemistry Chemical Physics
• Print ISSN: 1463-9076
• Electronic ISSN: 1463-9084
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 17
• Issue: 17
• Pages: 11586-11592
• DOI: https://doi.org/10.1039/c5cp01307k
• Public URL: https://nottingham-repository.worktribe.com/output/1431493
• Publisher URL: https://pubs.rsc.org/en/Content/ArticleLanding/2015/CP/C5CP01307K#!divAbstract
• Related Public URLs: https://arxiv.org/abs/1503.01668