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Visualizing charge separation in bulk heterojunction organic solar cells

Vithanage, D. Amarasinghe; Devi�is, A.; Abramavi?ius, V.; Infahsaeng, Y.; Abramavi?ius, D.; MacKenzie, R.C.I.; Keivanidis, P.E.; Yartsev, A.; Hertel, D.; Nelson, J.; Sundstr�m, V.; Gulbinas, V.


D. Amarasinghe Vithanage

A. Devi�is

V. Abramavi?ius

Y. Infahsaeng

D. Abramavi?ius

R.C.I. MacKenzie

P.E. Keivanidis

A. Yartsev

D. Hertel

J. Nelson

V. Sundstr�m

V. Gulbinas


Solar cells based on conjugated polymer and fullerene blends have been developed as a low-cost alternative to silicon. For efficient solar cells, electron–hole pairs must separate into free mobile charges that can be extracted in high yield. We still lack good understanding of how, why and when carriers separate against the Coulomb attraction. Here we visualize the charge separation process in bulk heterojunction solar cells by directly measuring charge carrier drift in a polymer:fullerene blend with ultrafast time resolution. We show that initially only closely separated (less than 1 nm) charge pairs are created and they separate by several nanometres during the first several picoseconds. Charge pairs overcome Coulomb attraction and form free carriers on a subnanosecond time scale. Numerical simulations complementing the experimental data show that fast three-dimensional charge diffusion within an energetically disordered medium, increasing the entropy of the system, is sufficient to drive the charge separation process.


Vithanage, D. A., Devižis, A., Abramavičius, V., Infahsaeng, Y., Abramavičius, D., MacKenzie, R., …Gulbinas, V. (2013). Visualizing charge separation in bulk heterojunction organic solar cells. Nature Communications, 4, Article 2334.

Journal Article Type Article
Acceptance Date Jul 22, 2013
Online Publication Date Aug 15, 2013
Publication Date Dec 22, 2013
Deposit Date Oct 30, 2018
Publicly Available Date Oct 30, 2018
Journal Nature Communications
Publisher Nature Publishing Group
Peer Reviewed Peer Reviewed
Volume 4
Article Number 2334
Public URL
Publisher URL


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