Juliano Katrib
Facile Determination of Molecular Structure Trends in Amphiphilic Core Corona Star Polymer Synthesis via Dielectric Property Measurement
Katrib, Juliano; Irvine, Derek; Hild, Frederic; Nguyen, Nam; Deng, Eileen; Dimitrakis, Georgios; Lau, Phei-Li
Authors
DEREK IRVINE derek.irvine@nottingham.ac.uk
Professor of Materials Chemistry
Frederic Hild
Nam Nguyen
Eileen Deng
GEORGIOS DIMITRAKIS GEORGIOS.DIMITRAKIS@NOTTINGHAM.AC.UK
Associate Professor
Phei-Li Lau
Abstract
The use of dielectric property measurements to define specific trends in the molecular structures of poly(caprolactone) containing star polymers and/or the interbatch repeatability of the synthetic procedures used to generate them is demonstrated. The magnitude of the dielectric property value is shown to accurately reflect: (a) the number of functional groups within a series of materials with similar molecular size when no additional intermolecular order is present in the medium, (b) the polymer molecular size for a series of materials containing a fixed core material and so functional group number, and/or (c) the batch to batch repeatability of the synthesis method. The dielectric measurements are validated by comparison to spectroscopic/chromatographic data.
Journal Article Type | Article |
---|---|
Acceptance Date | May 31, 2016 |
Online Publication Date | Jun 17, 2016 |
Publication Date | 2016-08 |
Deposit Date | Sep 18, 2018 |
Print ISSN | 1022-1336 |
Publisher | Wiley |
Peer Reviewed | Peer Reviewed |
Volume | 37 |
Issue | 15 |
Pages | 1295-1299 |
DOI | https://doi.org/10.1002/marc.201600149 |
Public URL | https://nottingham-repository.worktribe.com/output/1115209 |
Publisher URL | https://onlinelibrary.wiley.com/doi/full/10.1002/marc.201600149 |
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