Guang Yang
Near-infrared-shielding energy-saving borosilicate glass-ceramic window materials based on doping of defective tantalum tungsten oxide (Ta0.3W0.7O2.85) nanocrystals
Yang, Guang; Liu, Yongwei; Yang, Chuanfan; Xia, Fang; Hu, Daming; Wu, Yupeng; Yaroslav, Shpotyuk; Takats, Viktor; He, Xiaoyan
Authors
Yongwei Liu
Chuanfan Yang
Fang Xia
Daming Hu
YUPENG WU yupeng.wu@nottingham.ac.uk
Professor of Building Physics
Shpotyuk Yaroslav
Viktor Takats
Xiaoyan He
Abstract
NIR-shielding window materials were fabricated by direct embedding of Ta0.3W0.7O2.85 nanocrystals in bulk borosilicate glass-ceramics during a facile melt-quenching process. Optical and thermal performance of the prepared windows can be adjusted by varying the concentration of H2WO4 and Ta2O5 in the starting materials. The optimized window fabricated from raw materials containing 4.5 mol% H2WO4 and 0.3 mol% Ta2O5 exhibited high visible light transmittance 74.4% and strong NIR-shielding ability ΔT = 68.9%. Its thermal insulation performance is much better than soda lime glass or ITO glass, and its visible light transmission is higher than cesium-tungsten-bronze-based film coated glass. The distribution of Ta0.3W0.7O2.85 functional nanocrystals in the glass matrix was confirmed by sample characterization using XRD, Raman, XPS, HRTEM and EDS. The NIR-shielding property has been attributed to local surface plasmon resonance due to oxygen vacancies in the Ta0.3W0.7O2.85 nanocrystals. This study sheds a light on fabricating energy-saving windows with a tunable NIR-shielding performance.
Journal Article Type | Article |
---|---|
Acceptance Date | Sep 1, 2022 |
Online Publication Date | Sep 6, 2022 |
Publication Date | Jan 1, 2023 |
Deposit Date | Sep 12, 2022 |
Publicly Available Date | Sep 7, 2023 |
Journal | Ceramics International |
Print ISSN | 0272-8842 |
Publisher | Elsevier BV |
Peer Reviewed | Peer Reviewed |
Volume | 49 |
Issue | 1 |
Pages | 403-412 |
DOI | https://doi.org/10.1016/j.ceramint.2022.09.003 |
Keywords | Materials Chemistry, Surfaces, Coatings and Films, Process Chemistry and Technology, Ceramics and Composites, Electronic, Optical and Magnetic Materials |
Public URL | https://nottingham-repository.worktribe.com/output/10920283 |
Publisher URL | https://www.sciencedirect.com/science/article/pii/S0272884222031649?via%3Dihub |
Additional Information | This article is maintained by: Elsevier; Article Title: Near-infrared-shielding energy-saving borosilicate glass-ceramic window materials based on doping of defective tantalum tungsten oxide (Ta0.3W0.7O2.85) nanocrystals; Journal Title: Ceramics International; CrossRef DOI link to publisher maintained version: https://doi.org/10.1016/j.ceramint.2022.09.003; Content Type: article; Copyright: © 2022 Published by Elsevier Ltd. |
Files
1-s2.0-S0272884222031649-main
(12.3 Mb)
PDF
Publisher Licence URL
https://creativecommons.org/licenses/by/4.0/
You might also like
Fluidisable mesoporous silica composites for thermochemical energy storage
(2023)
Journal Article
Preliminary investigation on the human response to patterned chromatic glazing
(2022)
Journal Article
Downloadable Citations
About Repository@Nottingham
Administrator e-mail: discovery-access-systems@nottingham.ac.uk
This application uses the following open-source libraries:
SheetJS Community Edition
Apache License Version 2.0 (http://www.apache.org/licenses/)
PDF.js
Apache License Version 2.0 (http://www.apache.org/licenses/)
Font Awesome
SIL OFL 1.1 (http://scripts.sil.org/OFL)
MIT License (http://opensource.org/licenses/mit-license.html)
CC BY 3.0 ( http://creativecommons.org/licenses/by/3.0/)
Powered by Worktribe © 2024
Advanced Search