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Precursor engineering of hydrotalcite-derived redox sorbents for reversible and stable thermochemical oxygen storage

High, Michael; Patzschke, Clemens F.; Zheng, Liya; Zeng, Dewang; Gavalda-Diaz, Oriol; Ding, Nan; Chien, Ka Ho Horace; Zhang, Zili; Wilson, George E.; Berenov, Andrey V.; Skinner, Stephen J.; Sedransk Campbell, Kyra L.; Xiao, Rui; Fennell, Paul S.; Song, Qilei

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Authors

Michael High

Clemens F. Patzschke

Liya Zheng

Dewang Zeng

Oriol Gavalda-Diaz

Nan Ding

Ka Ho Horace Chien

Zili Zhang

George E. Wilson

Andrey V. Berenov

Stephen J. Skinner

Kyra L. Sedransk Campbell

Rui Xiao

Paul S. Fennell

Qilei Song



Abstract

Abstract: Chemical looping processes based on multiple-step reduction and oxidation of metal oxides hold great promise for a variety of energy applications, such as CO2 capture and conversion, gas separation, energy storage, and redox catalytic processes. Copper-based mixed oxides are one of the most promising candidate materials with a high oxygen storage capacity. However, the structural deterioration and sintering at high temperatures is one key scientific challenge. Herein, we report a precursor engineering approach to prepare durable copper-based redox sorbents for use in thermochemical looping processes for combustion and gas purification. Calcination of the CuMgAl hydrotalcite precursors formed mixed metal oxides consisting of CuO nanoparticles dispersed in the Mg-Al oxide support which inhibited the formation of copper aluminates during redox cycling. The copper-based redox sorbents demonstrated enhanced reaction rates, stable O2 storage capacity over 500 redox cycles at 900 °C, and efficient gas purification over a broad temperature range. We expect that our materials design strategy has broad implications on synthesis and engineering of mixed metal oxides for a range of thermochemical processes and redox catalytic applications.

Citation

High, M., Patzschke, C. F., Zheng, L., Zeng, D., Gavalda-Diaz, O., Ding, N., …Song, Q. (2022). Precursor engineering of hydrotalcite-derived redox sorbents for reversible and stable thermochemical oxygen storage. Nature Communications, 13(1), Article 5109. https://doi.org/10.1038/s41467-022-32593-6

Journal Article Type Article
Acceptance Date Aug 1, 2022
Online Publication Date Aug 30, 2022
Publication Date Aug 30, 2022
Deposit Date May 3, 2023
Publicly Available Date May 9, 2023
Journal Nature Communications
Publisher Nature Publishing Group
Peer Reviewed Peer Reviewed
Volume 13
Issue 1
Article Number 5109
DOI https://doi.org/10.1038/s41467-022-32593-6
Keywords Article, /639/4077/4057, /639/301/299/1013, /639/925/357/354, /639/166/898, /128, /123, /145, /147, /147/137, article
Public URL https://nottingham-repository.worktribe.com/output/10907003
Publisher URL https://www.nature.com/articles/s41467-022-32593-6#citeas
Additional Information Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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