Manipulating and probing the polarisation of a methyl tunnelling system by field-cycling NMR
(2017)
Journal Article
Zhang, B., Abu-Khumra, S., Aibout, A., & Horsewill, A. J. (2017). Manipulating and probing the polarisation of a methyl tunnelling system by field-cycling NMR. Journal of Chemical Physics, 146(6), Article 064302. https://doi.org/10.1063/1.4975173
In NMR the polarisation of the Zeeman system may be routinely probed and manipulated by applying resonant rf pulses. As with spin-½ nuclei, at low temperature the quantum tunnelling states of a methyl rotor are characterised by two energy levels and... Read More about Manipulating and probing the polarisation of a methyl tunnelling system by field-cycling NMR.