Outputs (114)

Perylene‐Grafted Silicas: Mechanistic Study and Applications in Heterogeneous Photoredox Catalysis (2019)
Journal Article
Carrillo, A. I., Elhage, A., Marin, M. L., & Lanterna, A. E. (2019). Perylene‐Grafted Silicas: Mechanistic Study and Applications in Heterogeneous Photoredox Catalysis. Chemistry - A European Journal, 25(65), 14928-14934. https://doi.org/10.1002/chem.201903539

A mechanistic study is herein presented for the use of heterogeneous photocatalysts based on perylene moieties. First, the successful immobilization of perylene diimides (PDI) on silica matrices is demonstrated, including their full characterization... Read More about Perylene‐Grafted Silicas: Mechanistic Study and Applications in Heterogeneous Photoredox Catalysis.

In vitro cytotoxicity assessment of monocationic and dicationic pyridinium-based ionic liquids on HeLa, MCF-7, BGM and EA.hy926 cell lines (2019)
Journal Article
Perez, S., Montalbán, M., Carissimi, G., Licence, P., & Villora, G. (2020). In vitro cytotoxicity assessment of monocationic and dicationic pyridinium-based ionic liquids on HeLa, MCF-7, BGM and EA.hy926 cell lines. Journal of Hazardous Materials, 385, Article 121513. https://doi.org/10.1016/j.jhazmat.2019.121513

Dicationic ionic liquids (ILs) generally possess higher thermal and electrochemical stability than the analogous monocationic ILs, which makes them more suitable for high-temperature applications as solvents for organic reactions, lubricants or stati... Read More about In vitro cytotoxicity assessment of monocationic and dicationic pyridinium-based ionic liquids on HeLa, MCF-7, BGM and EA.hy926 cell lines.

Decorated titania fibers as photocatalysts for hydrogen generation and organic matter degradation (2019)
Journal Article
Mapukata, S., Hainer, A. S., Lanterna, A. E., Scaiano, J. C., & Nyokong, T. (2020). Decorated titania fibers as photocatalysts for hydrogen generation and organic matter degradation. Journal of Photochemistry and Photobiology A: Chemistry, 388, Article 112185. https://doi.org/10.1016/j.jphotochem.2019.112185

Heterogenous photocatalysts based on electrospun fibers composed of polyvinylpyrrolidone and titanium propoxide were prepared and heated at 500, 750 and 950 °C to obtain anatase and rutile fibers. The fibers were then decorated with Pd and Co nanopar... Read More about Decorated titania fibers as photocatalysts for hydrogen generation and organic matter degradation.

Interaction between particles with inhomogeneous surface charge distributions: Revisiting the Coulomb fission of dication molecular clusters (2019)
Journal Article
Filippov, A. V., Chen, X., Harris, C., Stace, A. J., & Besley, E. (2019). Interaction between particles with inhomogeneous surface charge distributions: Revisiting the Coulomb fission of dication molecular clusters. Journal of Chemical Physics, 151(15), Article 154113. https://doi.org/10.1063/1.5119347

An analytical solution describing the electrostatic interaction between particles with inhomogeneous surface charge distributions has been developed. For particles, each carrying a single charge, the solution equates to the presence of a point charge... Read More about Interaction between particles with inhomogeneous surface charge distributions: Revisiting the Coulomb fission of dication molecular clusters.

Identification of separate isoenergetic routes for vibrational energy flow in p-fluorotoluene (2019)
Journal Article
Gardner, A. M., Whalley, L. E., Kemp, D. J., Tuttle, W. D., & Wright, T. G. (2019). Identification of separate isoenergetic routes for vibrational energy flow in p-fluorotoluene. Journal of Chemical Physics, 151(15), Article 154302. https://doi.org/10.1063/1.5126179

A deceptively simple feature in the S1 ← S0 spectrum of p-fluorotoluene (pFT), 1013 cm−1 above the origin, is studied using both zero-electron-kinetic-energy (ZEKE) and two-dimensional laser-induced fluorescence (2D-LIF) spectroscopy. It is found to... Read More about Identification of separate isoenergetic routes for vibrational energy flow in p-fluorotoluene.

Zinc 1s Valence-to-Core X-ray Emission Spectroscopy of Halozincate Complexes (2019)
Journal Article
Clarke, C. J., Hayama, S., Hawes, A., Hallett, J. P., Chamberlain, T. W., Lovelock, K. R., & Besley, N. A. (2019). Zinc 1s Valence-to-Core X-ray Emission Spectroscopy of Halozincate Complexes. Journal of Physical Chemistry A, 123(44), 9552-9559. https://doi.org/10.1021/acs.jpca.9b08037

The Zn 1s valence-to-core (VtC) X-ray emission spectra of seven ionic liquids have been measured experimentally and simulated on the basis of time-dependent density-functional theory (TDDFT) calculations. Six of the ionic liquids were made by mixing... Read More about Zinc 1s Valence-to-Core X-ray Emission Spectroscopy of Halozincate Complexes.

Ionic and Electronic Conduction in TiNb2O7 (2019)
Journal Article
Grey, C. P., Griffith, K. J., Seymour, I. D., Hope, M. A., Butala, M. M., Lamontagne, L. K., Preefer, M. B., Koçer, C. P., Henkelman, G., Morris, A. J., Cliffe, M. J., & Dutton, S. E. (2019). Ionic and Electronic Conduction in TiNb2O7. Journal of the American Chemical Society, 141(42), 16706–16725. https://doi.org/10.1021/jacs.9b06669

TiNb2O7 is a Wadsley–Roth phase with a crystallographic shear structure and is a promising candidate for high-rate lithium ion energy storage. The fundamental aspects of the lithium insertion mechanism and conduction in TiNb2O7, however, are not well... Read More about Ionic and Electronic Conduction in TiNb2O7.

Reversible coordinative binding and separation of sulfur dioxide in a robust metal–organic framework with open copper sites (2019)
Journal Article
Smith, G. L., Eyley, J. E., Han, X., Zhang, X., Li, J., Jacques, N. M., Godfrey, H. G. W., Argent, S. P., McCormick McPherson, L. J., Teat, S. J., Cheng, Y., Frogley, M. D., Cinque, G., Day, S. J., Tang, C. C., Easun, T. L., Rudić, S., Ramirez-Cuesta, A. J., Yang, S., & Schröder, M. (2019). Reversible coordinative binding and separation of sulfur dioxide in a robust metal–organic framework with open copper sites. Nature Materials, 18(12), 1358-1365. https://doi.org/10.1038/s41563-019-0495-0

Emissions of SO2 from flue gas and marine transport have detrimental impacts on the environment and human health, but SO2 is also an important industrial feedstock if it can be recovered, stored and transported efficiently. Here we report the excepti... Read More about Reversible coordinative binding and separation of sulfur dioxide in a robust metal–organic framework with open copper sites.

The effect of coordination of alkanes, Xe and CO2 (η1-OCO) on changes in spin state and reactivity in organometallic chemistry: a combined experimental and theoretical study of the photochemistry of CpMn(CO)3 (2019)
Journal Article
Wu, X., Liu, Z., Murphy, T. S., Sun, X. Z., Hanson-Heine, M. W. D., Towrie, M., Harvey, J. N., & George, M. W. (2019). The effect of coordination of alkanes, Xe and CO2 (η1-OCO) on changes in spin state and reactivity in organometallic chemistry: a combined experimental and theoretical study of the photochemistry of CpMn(CO)3. Faraday Discussions, 220, 86-104. https://doi.org/10.1039/c9fd00067d

A combined experimental and theoretical study is presented of several ligand addition reactions of the triplet fragment 3CpMn(CO)2 formed upon photolysis of CpMn(CO)3. Experimental data are provided for reactions in n-heptane and perfluoromethylcyclo... Read More about The effect of coordination of alkanes, Xe and CO2 (η1-OCO) on changes in spin state and reactivity in organometallic chemistry: a combined experimental and theoretical study of the photochemistry of CpMn(CO)3.

In search of effective therapies to overcome resistance to Temozolomide in brain tumours (2019)
Journal Article
Grundy, R., Bouzinab, K., Summers, H., Zhang, J., Stevens, M. F. G., Moody, C. J., Turyanska, L., Thomas, N. R., Gershkovich, P., Ashford, M. B., Vitterso, E., Storer, L. C. D., & Bradshaw, T. D. (2019). In search of effective therapies to overcome resistance to Temozolomide in brain tumours. Cancer Drug Resistance, 2(4), 1018-1031. https://doi.org/10.20517/cdr.2019.64

Glioblastoma multiforme is the most common and lethal brain tumour-type. The current standard of care includes Temozolomide (TMZ) chemotherapy. However, inherent and acquired resistance to TMZ thwart successful treatment. The direct repair protein me... Read More about In search of effective therapies to overcome resistance to Temozolomide in brain tumours.