Outputs (3)

Host–Guest Hybrid Redox Materials Self‐Assembled from Polyoxometalates and Single‐Walled Carbon Nanotubes (2019)
Journal Article
Jordan, J. W., Lowe, G. A., McSweeney, R. L., Stoppiello, C. T., Lodge, R. W., Skowron, S. T., Biskupek, J., Rance, G. A., Kaiser, U., Walsh, D. A., Newton, G. N., & Khlobystov, A. N. (2019). Host–Guest Hybrid Redox Materials Self‐Assembled from Polyoxometalates and Single‐Walled Carbon Nanotubes. Advanced Materials, 31(41), Article 1904182. https://doi.org/10.1002/adma.201904182

The development of next‐generation molecular‐electronic, electrocatalytic, and energy‐storage systems depends on the availability of robust materials in which molecular charge‐storage sites and conductive hosts are in intimate contact. It is shown he... Read More about Host–Guest Hybrid Redox Materials Self‐Assembled from Polyoxometalates and Single‐Walled Carbon Nanotubes.

Efficient Electrocatalytic CO2 Reduction Driven by Ionic Liquid Buffer‐Like Solutions (2019)
Journal Article
Goncalves, W. D. G., Zanatta, M., Simon, N. M., Rutzen, L. M., Walsh, D. A., & Dupont, J. (2019). Efficient Electrocatalytic CO2 Reduction Driven by Ionic Liquid Buffer‐Like Solutions. ChemSusChem, 12(18), 4170-4175. https://doi.org/10.1002/cssc.201901076

We show here that electrocatalysis of CO2 reduction in aqueous electrolytes containing the ionic liquid (IL) 1-n-butyl-2,3dimethylimidazolium acetate ([BMMIm][OAc]) and dimethyl sulfoxide (DMSO) proceeds at low overpotentials (−0.9 V vs. Ag/AgCl) at... Read More about Efficient Electrocatalytic CO2 Reduction Driven by Ionic Liquid Buffer‐Like Solutions.

Tuning the Reactivity of TEMPO during Electrocatalytic Alcohol Oxidations in Room-Temperature Ionic Liquids (2019)
Journal Article
Delorme, A. E., Sans, V., Licence, P., & Walsh, D. A. (2019). Tuning the Reactivity of TEMPO during Electrocatalytic Alcohol Oxidations in Room-Temperature Ionic Liquids. ACS Sustainable Chemistry and Engineering, 7(13), 11691-11699. https://doi.org/10.1021/acssuschemeng.9b01823

2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) is a promising, sustainable, metal-free mediator for oxidation of alcohols. In this contribution, we describe how the selectivity of TEMPO for electrocatalytic alcohol oxidations in room-temperature ionic... Read More about Tuning the Reactivity of TEMPO during Electrocatalytic Alcohol Oxidations in Room-Temperature Ionic Liquids.