Outputs (15)

Single-molecule imaging and kinetic analysis of intermolecular polyoxometalate reactions (2021)
Journal Article
Jordan, J. W., Fung, K. L. Y., Skowron, S. T., Allen, C. S., Biskupek, J., Newton, G. N., Kaiser, U., & Khlobystov, A. N. (2021). Single-molecule imaging and kinetic analysis of intermolecular polyoxometalate reactions. Chemical Science, 12(21), 7377-7387. https://doi.org/10.1039/d1sc01874d

We induce and study reactions of polyoxometalate (POM) molecules, [PW12O40]3− (Keggin) and [P2W18O62]6− (Wells–Dawson), at the single-molecule level. Several identical carbon nanotubes aligned side by side within a bundle provided a platform for spat... Read More about Single-molecule imaging and kinetic analysis of intermolecular polyoxometalate reactions.

Polaritonic Enhancement of Near-Field Scattering of Small Molecules Encapsulated in Boron Nitride Nanotubes: Chemical Reactions in Confined Spaces (2021)
Journal Article
Datz, D., Németh, G., Walker, K. E., Rance, G. A., Pekker, Á., Khlobystov, A. N., & Kamarás, K. (2021). Polaritonic Enhancement of Near-Field Scattering of Small Molecules Encapsulated in Boron Nitride Nanotubes: Chemical Reactions in Confined Spaces. ACS Applied Nano Materials, 4(5), 4335–4339. https://doi.org/10.1021/acsanm.1c00064

Nanotubes have been extensively utilized as nanocontainers for molecules and as nanoreactors for chemical reactions in confinement, with the potential for applications in hydrogen storage and catalysis. We show that phonon polaritons of boron nitride... Read More about Polaritonic Enhancement of Near-Field Scattering of Small Molecules Encapsulated in Boron Nitride Nanotubes: Chemical Reactions in Confined Spaces.

π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons (2021)
Journal Article
Martínez‐Abadía, M., Strutyński, K., Lerma‐Berlanga, B., Stoppiello, C. T., Khlobystov, A. N., Martí‐Gastaldo, C., Saeki, A., Melle‐Franco, M., & Mateo‐Alonso, A. (2021). π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons. Angewandte Chemie International Edition, 60(18), 9941-9946. https://doi.org/10.1002/anie.202100434

Three-dimensional covalent organic frameworks (3D COFs) with a pcu topology have been obtained from distorted polycyclic aromatic hydrocarbons acting as triangular antiprismatic (D3d) nodes. Such 3D COFs are six-fold interpenetrated as the result of... Read More about π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons.

Understanding charge transport in wavy 2D covalent organic frameworks (2021)
Journal Article
Martínez-Abadía, M., Strutyński, K., Stoppiello, C. T., Lerma Berlanga, B., Martí-Gastaldo, C., Khlobystov, A. N., Saeki, A., Melle-Franco, M., & Mateo-Alonso, A. (2021). Understanding charge transport in wavy 2D covalent organic frameworks. Nanoscale, 13(14), 6829-6833. https://doi.org/10.1039/d0nr08962a

Understanding charge transport in 2D covalent organic frameworks is crucial to increase their performance. Herein a new wavy 2D covalent organic framework has been designed, synthesized and studied to shine light on the structural factors that domina... Read More about Understanding charge transport in wavy 2D covalent organic frameworks.

Kerogen nanoscale structure and CO2 adsorption in shale micropores (2021)
Journal Article
Gonciaruk, A., Hall, M. R., Fay, M. W., Parmenter, C. D. J., Vane, C. H., Khlobystov, A. N., & Ripepi, N. (2021). Kerogen nanoscale structure and CO2 adsorption in shale micropores. Scientific Reports, 11, Article 3920. https://doi.org/10.1038/s41598-021-83179-z

Gas storage and recovery processes in shales critically depend on nano-scale porosity and chemical composition, but information about the nanoscale pore geometry and connectivity of kerogen, insoluble organic shale matter, is largely unavailable. Usi... Read More about Kerogen nanoscale structure and CO2 adsorption in shale micropores.